Results 181 to 190 of about 385,491 (269)

Combining photo-CIDNP and long-lived spin states enables high-contrast detection of weak protein-ligand interactions.

open access: yesPhys Chem Chem Phys
Bütikofer M   +6 more
europepmc   +1 more source

Photochemical activation of pincer-ligated phosphoranides: mechanistic insight for reduction of aryl halides. [PDF]

open access: yesChem Sci
Escoudé E   +7 more
europepmc   +1 more source

Chemical Syntheses of 3′ and 5′ Phosphorylated Oligonucleotides: An Overview

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 21, 4 June 2026.
This review provides an overview of the various chemical methods employed in the synthesis of oligonucleotides bearing a phosphate group at their 3′ or 5′ end. Notably, it presents modified phosphoramidites and supports developed for this purpose. Oligonucleotides (ON) with a phosphate monoester group at their 3′ or 5′ end have applications in many ...
Rémy Lartia
wiley   +1 more source

Gold(I)‐Catalyzed C(sp3)–C(sp) Cross‐Coupling: Access to Alkynylated Tetrahydrofuran Derivatives

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 11, 3 June 2026.
An Au(I)‐catalyzed C(sp3)–C(sp) cross‐coupling, unsuccessful under photosensitized conditions for vinylgold(I) complexes, is achieved using MeDalPhosAuCl under thermal conditions, giving alkynylated tetrahydrofuran derivatives. The reaction proceeds via an Au(III) intermediate formed by oxidative addition of an alkynyl iodide.
Jorge C. Herrera‐Luna   +7 more
wiley   +1 more source

Rhodium(I)‐Catalyzed P(III)‐Directed C–H Alkylation of Biarylphosphines With Maleimides

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 11, 3 June 2026.
A Rh(I)‐catalyzed P(III)‐directed ortho‐C–H bond alkylation of biarylphosphines with maleimides is disclosed. The reaction accommodates substituted alkenes, proceeds efficiently on gram scale, and consistently generates diastereomeric phosphines. NMR and mechanistic studies reveal that the stereochemical outcome arises from conformational restriction ...
Jian Zhang   +4 more
wiley   +1 more source

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