Photochemical activation of pincer-ligated phosphoranides: mechanistic insight for reduction of aryl halides. [PDF]
Escoudé E +7 more
europepmc +1 more source
Chemical Syntheses of 3′ and 5′ Phosphorylated Oligonucleotides: An Overview
This review provides an overview of the various chemical methods employed in the synthesis of oligonucleotides bearing a phosphate group at their 3′ or 5′ end. Notably, it presents modified phosphoramidites and supports developed for this purpose. Oligonucleotides (ON) with a phosphate monoester group at their 3′ or 5′ end have applications in many ...
Rémy Lartia
wiley +1 more source
Synthesis of Insect Sex Pheromones by Ligand-Free Iron-Catalyzed Alkyl-Allyl Cross-Coupling Involving α,ω-Difunctionalized Aliphatic Grignard Nucleophiles and Allyl Electrophiles. [PDF]
Tintar A +4 more
europepmc +1 more source
Gold(I)‐Catalyzed C(sp3)–C(sp) Cross‐Coupling: Access to Alkynylated Tetrahydrofuran Derivatives
An Au(I)‐catalyzed C(sp3)–C(sp) cross‐coupling, unsuccessful under photosensitized conditions for vinylgold(I) complexes, is achieved using MeDalPhosAuCl under thermal conditions, giving alkynylated tetrahydrofuran derivatives. The reaction proceeds via an Au(III) intermediate formed by oxidative addition of an alkynyl iodide.
Jorge C. Herrera‐Luna +7 more
wiley +1 more source
Multicatalytic Access to Renewable Poly(Silyl Ether)s with Tunable Properties. [PDF]
Yang F, Sun F, Thomas CM.
europepmc +1 more source
Rhodium(I)‐Catalyzed P(III)‐Directed C–H Alkylation of Biarylphosphines With Maleimides
A Rh(I)‐catalyzed P(III)‐directed ortho‐C–H bond alkylation of biarylphosphines with maleimides is disclosed. The reaction accommodates substituted alkenes, proceeds efficiently on gram scale, and consistently generates diastereomeric phosphines. NMR and mechanistic studies reveal that the stereochemical outcome arises from conformational restriction ...
Jian Zhang +4 more
wiley +1 more source
Rapid and Accurate Determination of <sup>226</sup>Ra from Drinking Water Using Macropa-Mediated Cloud Point Extraction Coupled with ICP-MS/MS. [PDF]
Govindaraj J +5 more
europepmc +1 more source
Using CEST NMR to discover previously unobserved states on the free energy surface of proteins: Application to the L99A cavity mutant of T4 lysozyme. [PDF]
Tiwari VP +5 more
europepmc +1 more source

