Results 271 to 280 of about 182,622 (338)

Quantum Chemistry Investigation of Linear and Nonlinear (chir)optical Properties of Oligoamide Foldamers

open access: yesChemistryEurope, EarlyView.
The linear and nonlinear (chir)optical properties of four oligoamide foldamers with different donor groups are studied by means of time‐dependent density functional theory calculations. It is shown that stronger donors yield larger hyperpolarizabilities due to low‐lying charge–transfer states. The agreement with the experiments concerning the key bands
Komlanvi Sèvi Kaka   +5 more
wiley   +1 more source

Enantioselective Synthesis of Sulfinamidines via Asymmetric Rhodium–Catalyzed Imidation of Sulfenamides

open access: yesChemistryEurope, EarlyView.
In this work, a catalytic enantioselective imidation approach is presented for the preparation of enantioenriched sulfinamidines from sulfenamides, employing a chiral dirhodium(II) tetracarboxylate catalyst. This method enables the imidation of N,N‐bisalkyl sulfenamides in yields of up to 98% and enantiomeric ratios up to 98:2, with a catalyst loading ...
Michael Andresini   +7 more
wiley   +1 more source

Phase‐Pure 2D Interfacial Perovskite Passivation for Stable and Efficient Photovoltaics

open access: yesCarbon Energy, EarlyView.
Phase‐pure 2D interfacial passivation eliminates mixed‐phase energetic disorder, establishes favorable band alignment, and suppresses interfacial non‐radiative recombination. This review elucidates deterministic phase‐purity control, defect and lattice reconstruction mechanisms, and scalable manufacturing strategies, highlighting how phase‐pure 2D/3D ...
Ming‐Xin Li   +9 more
wiley   +1 more source

Dipolar Molecular Motor Candidates with Planar Chirality

open access: yesChemistry – A European Journal, EarlyView.
Two prototypes of molecular motors with simultaneous implementation of planar chirality and a permanent dipole have been designed and synthesized in 7 steps with overall yields of 2.8 to 5.5%. Abstract Two molecular motor candidates built around ruthenium(II) centers featuring both planar chirality and a permanent dipole have been synthesized in seven ...
Thomas A. Hector   +5 more
wiley   +1 more source

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