Results 201 to 210 of about 67,573 (304)
NiH‐Catalyzed Enantio‐ and Regioselective Hydroselenylation of Unactivated Alkenes
Nickel‐hydride‐catalyzed enantio‐ and regioselective hydroselenylation of unactivated alkenes provides access to chiral organoselenium compounds. Enantiodetermining Ni–H insertion followed by single‐electron diselenide activation generates selenyl radical.
Hyung‐Joon Kang +2 more
wiley +1 more source
Direct demonstration of electric chirality control in a helimagnetic YMn<sub>6</sub>Sn<sub>6</sub> by spin-polarized neutron scattering. [PDF]
Masuda H +5 more
europepmc +1 more source
Transparent Topological Meta‐Diplexer via Tightly Confined Valley Surface States
An optically transparent topological metasurface supporting tightly confined valley surface states enables robust and flexible wave routing in an ultrathin platform. A compact transparent meta‐diplexer with spatially and spectrally separated channels is realized, while communication experiments verify high‐fidelity signal transmission, opening new ...
Sijie Li +5 more
wiley +1 more source
External pressure directly tunes the breathing distortion of the kagome lattice in Fe3Sn2, suppressing it near 15 GPa and reversing it at higher pressures. This structural modulation drives a cascade of Lifshitz transitions, reconstructs the Fermi surface, strengthens electronic correlations and carrier localization, and modifies ultrafast electron ...
Marcos Vinicius Gonçalves‐Faria +14 more
wiley +1 more source
Task-adaptive multimodal molecular representations for structure-sensitive property prediction. [PDF]
Lin S +13 more
europepmc +1 more source
Enantioselective Access to Trifluoromethylated Spirocyclopropyl Heterocycles
We report a rhodium‐catalyzed asymmetric [2+1] spirocyclopropanation of methylene azacycles with trifluoromethyl carbenes in situ derived from fluoroalkyl triftosylhydrazones. ABSTRACT Chiral spirocyclopropyl heterocycles have emerged as privileged three‐dimensional structural motifs in medicinal chemistry.
Yuanhao Zhu +9 more
wiley +1 more source
Pre-Crosslinked Network-Mediated Dual Exchange Enables Boosting Chiroptical Activity and Decoupled Two-Level Chirality in Covalent Organic Frameworks. [PDF]
Zha X +10 more
europepmc +1 more source
An integrated polarimetry architecture based on a cholesteric liquid crystal waveguide polarization splitter overcomes the volumetric bottleneck in chip‐scale atomic magnetometers. By leveraging Bragg‐selective reflection and total‐internal‐reflection‐induced helicity inversion, this ultrathin device enables efficient circular polarization splitting ...
Zhibo Cui +9 more
wiley +1 more source

