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Screening for generality in asymmetric catalysis [PDF]

open access: yesNature, 2022
Research in the field of asymmetric catalysis over the past half century has resulted in landmark advances, enabling the efficient synthesis of chiral building blocks, pharmaceuticals, and natural products. A small number of asymmetric catalytic reactions have been identified that display high selectivity across a broad scope of substrates; not ...
Eugene Kwan   +2 more
exaly   +4 more sources

Aggregation-Induced Catalysis: Asymmetric Catalysis with Chiral Aggregates [PDF]

open access: yesResearch, 2023
So far, there have been 4 methods to control chirality including the use of chiral auxiliaries, reagents, solvents, and catalysts documented in literature and textbooks.
Yao Tang   +9 more
doaj   +2 more sources

Asymmetric Catalysis

open access: yesCHIMIA, 1999
Our main research interests are in the areas of homogeneous and heterogeneous asymmetric catalysis, focusing on the development of new classes of chiral ligands for the enantiocontrol of metal-catalyzed reactions.
Andreas Pfaltz
doaj   +2 more sources

Ultra-high-throughput mapping of the chemical space of asymmetric catalysis enables accelerated reaction discovery [PDF]

open access: yesNature Communications, 2023
The discovery of highly enantioselective catalysts and elucidating their generality face great challenges due to the complex multidimensional chemical space of asymmetric catalysis and inefficient screening methods.
Wenjing Nie   +5 more
doaj   +2 more sources

Cooperative Photoredox and Asymmetric Catalysis

open access: yesCHIMIA, 2016
Chemical processes combining visible-light-activated redox catalysis with asymmetric catalysis are reviewed, including enamine catalysis in the presence or absence of an additional photoredox sensitizer, phase transfer catalysis exploiting an in
Haohua Huo, Eric Meggersa
doaj   +4 more sources

Recent Advances in Carbon-Based Catalysts for Heterogeneous Asymmetric Catalysis [PDF]

open access: yesMolecules
Carbon materials, including graphene, carbon nanotubes, and fullerenes, serve as effective supports for catalysts and play a pivotal role in heterogeneous asymmetric catalysis due to their unique properties and ability to create defined environments for ...
Yidan Zheng   +3 more
doaj   +2 more sources

Synthesis of Homochiral N‐Heterocyclic Carbene‐Based Nanosheets for Enhanced Asymmetric Catalysis [PDF]

open access: yesAdvanced Science
Utilizing ultrathin 2D metal–organic framework nanosheets (2D MONs) as supports for incorporating chiral catalysts represents a highly promising avenue in the field of asymmetric catalysis.
Xinchao Wang   +6 more
doaj   +2 more sources

Heterobifunctional Rotaxanes for Asymmetric Catalysis. [PDF]

open access: yesAngew Chem Int Ed Engl, 2020
AbstractHeterobifunctional rotaxanes serve as efficient catalysts for the addition of malonates to Michael acceptors. We report a series of four different heterobifunctional rotaxanes, featuring an amine‐based thread and a chiral 1,1′‐binaphthyl‐phosphoric‐acid‐based macrocycle.
Pairault N   +6 more
europepmc   +5 more sources

Strategies in asymmetric catalysis [PDF]

open access: yesBeilstein Journal of Organic Chemistry, 2017
Tehshik P. Yoon
doaj   +3 more sources

Synthesis of novel phthalimido oxime pseudoesters and evaluation of their cytotoxicity [PDF]

open access: yesJournal of the Serbian Chemical Society, 2020
A series of novel optically pure oxime pseudoesters derivatives were synthesized by the reaction of substitute keto oximes with various N-substituted α-amino acids chlorides in the presence of triethylamine and dichloromethane at 0°C, and their ...
Mehrez Asma   +4 more
doaj   +1 more source

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