Results 71 to 80 of about 67,573 (304)

Nanoconfinement‐Induced Second‐Harmonic Circular Dichroism via Chirality–Ferroelectric Coupling

Advanced Functional Materials, EarlyView.
Nanoconfinement of a ferroelectric nematic liquid crystal within a chiral nanoporous sponge yields an enhanced second‐harmonic generation circular dichroism (|gSHG–CD| ≈ 1.1). Polarization‐resolved analysis suggests an additional magnetic‐dipole‐associated nonlinear contribution under nanoconfinement, highlighting chirality–ferroelectric coupling as a ...
Jae‐Jin Lee, Hiroya Nishikawa, Tae‐Woong Moon, Dong‐Ha Kim, Fumito Araoka, Suk‐Won Choi   +5 more
wiley   +1 more source

Chiral phosphoric acid-catalyzed asymmetric synthesis of helically chiral, planarly chiral and inherently chiral molecules

Beilstein Journal of Organic Chemistry
Chiral molecules, distinguished by nonsuperimposability with their mirror image, play crucial roles across diverse research fields. Molecular chirality is conventionally categorized into the following types: central chirality, axial chirality, planar ...
Wei Liu, Xiaoyu Yang
doaj   +1 more source

Chiral and Chirality Discrimination on Helical Polyacetylenes

Analytical Sciences, 2002
Synthesis and function of helical polyphenylacetylenes are briefly reviewed. Optically active helical polyphenylacetylenes were synthesized by polymerization of the corresponding chiral phenylacetylene monomers and their chiral recognition abilities were evaluated as a chiral stationary phase for HPLC.
openaire   +2 more sources

Modal Analysis of Light Propagation, Polarization and Diffraction by Cholesteric Liquid Crystal Layers

Advanced Functional Materials, EarlyView.
The analysis of optical eigenmodes in chiral liquid crystal with perpendicular or tilted helical axis, and their correspondence with the external medium, leads to an intuitive understanding of the angle and wavelength dependency of transmissive and reflective diffraction.
Ke Xu, Pouya Nosratkhah, Le Zhou, Shengzhu Yi, Giorgio Manzoni, Kristiaan Neyts   +5 more
wiley   +1 more source

Thermoresponsive Liquid Crystalline Polymer Coatings Programmed by Field‐Induced Topological Defects for Tunable Optical and Topographical Responses

Advanced Functional Materials, EarlyView.
Resonant standing waves generate large‐area lattices of liquid‐crystal topological defects that are permanently encoded into polymer coatings by photopolymerization. The preserved director architecture produces thermally reconfigurable surface topographies while maintaining programmable optical functionality, demonstrating a scalable strategy for ...
Jacques A. Peixoto, Mufeeduzaman Chavilkkadan, Alexander Fusi, Marko Beslać, Dirk J. Broer, Etienne Brasselet, Danqing Liu   +6 more
wiley   +1 more source

Chirally locked and dynamic bis-perylene diimide macrocycles with multiple sources of chirality

Communications Chemistry
Chiral organic materials show great promise in optoelectronics, sensing and catalysis. Among those, macrocycles are of great interest due to their preorganisation and potential amplification of chiroptical properties.
Denis Hartmann, Samuel E. Penty, Robert Pal, Timothy A. Barendt   +3 more
doaj   +1 more source

Examples of dynamic chirality in nuclei

EPJ Web of Conferences, 2018
In many cases the chirality was almost observed but the transition probabilities are different. This fact is clearly seen in the cases of 134Pr and 102Rh. In the case of chirality, the yrast and the side bands should be nearly degenerate.
Yavahchova M.S., Tonev D., Goutev N., de Angelis G., Bhowmik R.K., Singh R.P., Muralithar S., Madhavan N., Kumar R., Kumar Raju M., Kaur J., Mahanto G., Singh A., Kaur N., Garg R., Sukla A.   +15 more
doaj   +1 more source

CHIRAL LAGRANGIANS [PDF]

International Journal of Modern Physics A, 2002
An overview of the field of Chiral Lagrangians is given. This includes Chiral Perturbation Theory and resummations to extend it to higher energies, applications to the muon anomalous magnetic moment, ∊′/∊ and others.
openaire   +2 more sources

Anisotropic Phonon Dynamics and Directional Transport in Actinide Van der Waals Semiconductor Uranium Triselenide

Advanced Functional Materials, EarlyView.
USe3 is introduced as an actinide van der Waals semiconductor that mirrors the quasi‐one‐dimensional physics of transition‐metal trichalcogenides. Polarization‐resolved Raman spectroscopy on exfoliated flakes maps strong in‐plane phonon anisotropy and strain‐tunable mode shifts.
Aljoscha Söll, Valentino Jadriško, Sourav Dey, Nassima Benchtaber, Kalyan Sarkar, Borna Radatović, Jan Luxa, Fedor Lipilin, Kseniia Mosina, Vojtěch Kundrát, Jakub Zalesak, Jana Vejpravová, Martin Žáček, Szymon J. Zelewski, Nikolas Antonatos, Christoph Gadermaier, José J. Baldoví, Zdeněk Sofer   +17 more
wiley   +1 more source

Local Solvent Ordering Drives Supramolecular Chirality Inversion. [PDF]

Adv Sci (Weinh)
Local solvent organization is shown to govern supramolecular chirality by selecting distinct chiral assembly pathways. A subtle change in water‐DMSO composition reverses the helical sense of a chiral perylene bisimide, while heating induces an irreversible thermal inversion to a more stable enantiomorph.
Pal T, Singh A, Adhikari S, Mondal J, Chaudhuri D.   +4 more
europepmc   +2 more sources