Synthesis and applications of alkenyl chlorides (vinyl chlorides): a review. [PDF]
Beilstein J Org ChemInternational audienceAlkenyl chlorides constitute a synthetically valuable yet historically underexplored class of organohalides. First prepared in 1868 by Charles Friedel - best known for the Friedel-Crafts reaction - via the reaction of ketones with ...
Müller DS.
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Activation of Alkyl Chlorides Enabled by Zirconocene and Photoredox Catalysis [PDF]
, 2022 C–Cl bond cleavage of unactivated alkyl chlorides with zirconocene and photoredox catalysis has been achieved. The present protocol exhibited a broader scope of alkyl chlorides compared to the preceding methods with titanocene. This scope expansion could
Keisuke, Tanaka +4 more
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Photosensitized Nickel Catalysis Enabled Silyl Radical Mediated Direct Activation of Carbamoyl Chlorides to Access (Hetero)aryl Carbamides [PDF]
, 2021 The transformation of a readily available molecule to a medicinally relevant functionality is the heart of organic synthesis which literally unfolds new direction in the field of drug discovery and development. Accordingly, synthetic chemistry fraternity
Sudip, Maiti +3 more
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Nickel-Catalyzed Reductive Cross-Coupling of Heteroaryl Chlorides and Aryl Chlorides [PDF]
, 2021 We report a nickel-catalyzed cross-electrophile coupling reaction of aryl chlorides and heteroaryl chlorides enabled by a synergistic combination consisting of halide effects and the addition of a magnesium salt.
Mark Lautens +5 more
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Modular synthesis of alkyl chlorides via visible light mediat-ed dual catalyzed aryl-chlorination of alkenes [PDF]
, 2023 Alkyl chlorides are a class of versatile building blocks widely used to generate C(sp3)-rich scaffolds through transformation such as nucle-ophilic substitution, radical addition reactions and metal-catalyzed cross-coupling processes.
Daniel, Drazen +4 more
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Iridium-Catalyzed Addition of Aroyl Chlorides and Aliphatic Acid Chlorides to Terminal Alkynes [PDF]
, 2016 Iridium complexes show high catalytic activity in intermolecular additions of acid chlorides to terminal alkynes to afford valuable (Z)-β-chloro-α,β-unsaturated ketones. Ligands in the catalytic system play a crucial role in this reaction.
Jun Terao (1478968) +3 more
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Electroreductive Borylation of Unactivated (Hetero)Aryl Chlorides Without Light Using Cumulene Electrocatalysts [PDF]
, 2023 Single-electron transfer (SET) plays a critical role in many chemical processes, from organic synthesis to environmental remediation. However, the selective reduction of inert substrates (Ep/2 < −2 V vs Fc/Fc+), such as ubiqui-tous electron-neutral and ...
Jaehwan, Kim +4 more
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General and mild Ni0-catalyzed α-arylation of ketones using aryl chlorides [PDF]
, 2015 The authors thank the ERC (Advanced Researcher award-FUNCAT), 7th Framework Program NMP2-LA-2010-246461 (SYNFLOW), the EPSRC and King Saud University for funding.A general methodology for the α-arylation of ketones using a nickel catalyst has been ...
Slawin, Alexandra MZ +8 more
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Solid Salt Fluxes for Molten Aluminum Processing—A Review
Metals, 2023 Aluminum recycling is a promising solution to environmental and economic issues. Secondary aluminum production will rise in the near future; however, the process is not without challenges.
Veronica Milani, Giulio Timelli
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Journal of Environmental Engineering and Landscape Management, 2009 Growth kinetics, i.e. the relationship between specific growth rate and the concentration of a substrate, is one of the basic tools in the modelling of activated sludge community growth.
Audra Skaisgirienė +2 more
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