Results 121 to 130 of about 36,154 (154)
Abstract BACKGROUND Chlorinated aliphatic hydrocarbons such as trichloroethylene (TCE) are persistent groundwater contaminants due to improper disposal and low biodegradability. This work presents an innovative bioelectrochemical system for the integrated reductive/oxidative removal of TCE from contaminated water, implemented in a single tubular ...
Maria Presutti +5 more
wiley +1 more source
Reactivity of Rh(I) Complexes Toward Fluorinated Ethers: Activation of Inhalation Anesthetics
Reactions of the inhaled anesthetics and α‐fluorinated ethers sevoflurane, enflurane, and isoflurane with [Rh(H)(PEt3)3] led to versatile organometallic transformations including C(sp3)─F and C(sp3)─Cl bond cleavage and metal–halogen bond formation, a catalytic hydrodehalogenation reaction, as well as the generation of a unique fluorinated phosphonium ...
Soodeh Mollasalehi +2 more
wiley +1 more source
ABSTRACT The separation of light olefins is a crucial process in the petrochemical industry, and developing advanced adsorbent materials is very significant. Aluminum (Al) cluster‐based heterometallic frameworks possess great application prospects but have rarely been investigated for separation applications.
Song‐Yan Sui +4 more
wiley +1 more source
Abstract The Viking missions landed two spacecraft on Mars each equipped with a pyrolysis‐gas chromatograph‐mass spectrometer system capable of detecting signs of life. Although working as intended, detections of chloromethane and dichloromethane were initially attributed to terrestrial contamination.
A. Mojarro +11 more
wiley +1 more source
Beyond Bactericidal: Plasma Surface Engineering to Defeat Food Matrix‐Conditioning Layers
ABSTRACT The persistence of foodborne pathogens on industrial food contact surfaces continues to challenge global food safety despite advances in sanitation technologies. A central limitation of current antimicrobial strategies lies in their validation under simplified laboratory conditions that overlook the physicochemically driven formation of food ...
Rafael Bianchini Fulindi +2 more
wiley +1 more source
Chlorinated ethenes, frequently encountered contaminants in groundwater, are often found to be incompletely dechlorinated to dichloroethene and vinyl chloride, more toxic products that accumulate in the aquifer.
Tarnawski, Sonia-Estelle +4 more
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Per‐ethylene‐glycol (EG)‐functionalized resorcin[4]arenes containing 12, 16, and 20 EG groups namely compounds 1d, 1e, and 1f, respectively, were prepared and found to self‐assemble, in organic solvents, into hexameric capsules. These capsules are more dynamic than the ones prepared based on alkyl substituted resorcin[4]arenes.
Gangadhara Angajala +3 more
wiley +1 more source
Flavin Catalysts in Organic Synthesis
Flavins and their congeners are potent catalysts for organic synthesis inspired by enzymatic transformations. In addition to catalysis in the flavin ground state via covalent intermediates, the excited singlet and triplet states unlock applications including photooxidation, photoreduction, and energy transfer via sensitization.
Jan Freudenberg, Golo Storch
wiley +2 more sources
Synthetic Strategies for the Construction of Cyclobutane‐Fused Heterocycles
Cyclobutane‐fused heterocycles are important motifs commonly present in bioactive compounds, recognized for their rigid 3D structures that confer unique properties. However, synthesizing these compounds remains challenging. This review discusses current methods for their synthesis, such as photochemical, metal‐catalyzed, and Lewis acid‐mediated [2 + 2]
Michela Vargiu +2 more
wiley +1 more source
Competitive Sorption and Uptake of Chlorinated Contaminant Mixtures by Plants
Phytoremediation is a green technology that uses plants to treat contaminated soil and groundwater. During the decades, phytoremediation has been successfully applied to remediate chlorinated solvents in a variety of environmental media.
Wang, Chen
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