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Dual Element (C/Cl) Isotope Analysis Indicates Distinct Mechanisms of Reductive Dehalogenation of Chlorinated Ethenes and Dichloroethane in Dehalococcoides mccartyi Strain BTF08 With Defined Reductive Dehalogenase Inventories [PDF]

open access: yesFrontiers in Microbiology, 2020
Dehalococcoides mccartyi strain BTF08 has the unique property to couple complete dechlorination of tetrachloroethene and 1,2-dichloroethane to ethene with growth by using the halogenated compounds as terminal electron acceptor. The genome of strain BTF08
Steffi Franke   +4 more
doaj   +3 more sources

Evidence of microbial reductive dehalogenation in deep-sea cold seeps and its implications for biogeochemical cycles [PDF]

open access: yesMicrobiome
Background Reductive dehalogenation is crucial for halogen cycling and environmental remediation, yet its ecological role is not completely understood, especially in deep-sea environments. To address this gap, we investigated the diversity and expression
Yingchun Han   +13 more
doaj   +3 more sources

Cobamide-mediated enzymatic reductive dehalogenation via long-range electron transfer [PDF]

open access: yesNature Communications, 2017
Cobalamin-containing reductive dehalogenases from organohalide-respiring bacteria play a key role in the degradation of halogenated organic compounds. Here the authors proposed a catalytic mechanism for dehalogenation that relies on a long-range electron
Cindy Kunze   +6 more
doaj   +3 more sources

Homoacetogenesis in Deep-Sea Chloroflexi, as Inferred by Single-Cell Genomics, Provides a Link to Reductive Dehalogenation in Terrestrial Dehalococcoidetes [PDF]

open access: yesmBio, 2017
The deep marine subsurface is one of the largest unexplored biospheres on Earth and is widely inhabited by members of the phylum Chloroflexi. In this report, we investigated genomes of single cells obtained from deep-sea sediments of the Peruvian Margin,
Holly L. Sewell   +2 more
doaj   +3 more sources

Chlorine Isotope Effects from Isotope Ratio Mass Spectrometry Suggest Intramolecular C-Cl Bond Competition in Trichloroethene (TCE) Reductive Dehalogenation [PDF]

open access: yesMolecules, 2014
Chlorinated ethenes are prevalent groundwater contaminants. To better constrain (bio)chemical reaction mechanisms of reductive dechlorination, the position-specificity of reductive trichloroethene (TCE) dehalogenation was investigated.
Anat Bernstein   +2 more
exaly   +4 more sources

CdS-Based Hydrothermal Photocatalysts for Complete Reductive Dehalogenation of a Chlorinated Propionic Acid in Water by Visible Light [PDF]

open access: yesNanomaterials
Cadmium sulfide (CdS)-based photocatalysts are prepared following a hydrothermal procedure (with CdCl2 and thiourea as precursors). The HydroThermal material annealed (CdS-HTa) is crystalline with a band gap of 2.31 eV. Photoelectrochemical investigation
Martina Milani   +6 more
doaj   +2 more sources

Microbially-mediated halogenation and dehalogenation cycling of organohalides in the ocean [PDF]

open access: yesNature Communications
Microbially mediated organohalide cycling in the ocean has profound implications for global biogeochemical cycles and climate, but the geographic distribution and diversity of the halogenation-dehalogenation cycling microorganisms remain unknown.
Na Zhou   +8 more
doaj   +2 more sources

Original Synthesis of Fluorenyl Alcohol Derivatives by Reductive Dehalogenation Initiated by TDAE [PDF]

open access: yesMolecules, 2016
We report here a novel and easy-to-handle reductive dehalogenation of 9-bromofluorene in the presence of arylaldehydes and dicarbonyl derivatives to give the corresponding fluorenyl alcohol derivatives and Darzens epoxides as by-products in tetrakis ...
Alain Gamal Giuglio-Tonolo   +2 more
doaj   +2 more sources

Bacterial diversity and reductive dehalogenase redundancy in a 1,2-dichloroethane-degrading bacterial consortium enriched from a contaminated aquifer [PDF]

open access: yesMicrobial Cell Factories, 2010
Background Bacteria possess a reservoir of metabolic functionalities ready to be exploited for multiple purposes. The use of microorganisms to clean up xenobiotics from polluted ecosystems (e.g.
Wittebolle Lieven   +7 more
doaj   +4 more sources

Genome-resolved transcriptomics reveals novel PCE-dehalogenating bacteria from Aarhus Bay sediments [PDF]

open access: yesmSystems
Organohalide-respiring bacteria (OHRB) are keystone microbes in bioremediation of sites contaminated with organohalides and in natural halogen cycling.
Chen Zhang   +3 more
doaj   +2 more sources

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