Results 41 to 50 of about 3,576 (229)

Dynamic Active Site Evolution in Lanthanum‐Based Catalysts Dictates Ethane Chlorination Pathways

Angewandte Chemie, EarlyView.
LaOCl‐catalyzed C2H6 chlorination offers a low‐carbon route for polyvinyl chloride synthesis, yet structural evolution occurs under Cl2 conditions. We establish structural sensitivity in La‐catalyzed chlorination, and elucidate the size‐dependent chlorophilicity of LaCl3 and the role of hydroxyl groups in overchlorination, highlighting stabilization of
Yuting Li, Haifeng Qi, Zihan Zhu, Xia Wu, Nicholas F. Dummer, Stuart H. Taylor, Lei Ma, Xiaofeng Yang, Qinggang Liu, Graham J. Hutchings, Yanqiang Huang   +10 more
wiley   +2 more sources

Optimized Synthesis and Characterization of Janus RhSeCl with Uniform Anionic Valences, Nonlinear Optical and Optoelectronic Properties

Advanced Science, EarlyView.
Janus RhSeCl exhibits a facial heteroatom configuration and uniform anionic valences with Se and Cl in the −1 oxidation state, stabilizing the unique structure. The symmetry‐breaking nature enables promising nonlinear optical and optoelectronic performance, providing new insights into two–dimensional (2D) Janus materials and broadening their potential ...
Kefeng Liu, Xuelian Sun, Puxin Cheng, Zhiteng Li, Penghui Li, Donghan Jia, Shijing Zhao, Xin Yang, Xinyu Wang, Liangting Ye, Shengqing Xia, Shuo Zhang, Yu Chen, Tao Gan, Jiong Li, Xiao Zhang, Jialiang Xu, Anmin Nie, Bing Huang, Huiyang Gou   +19 more
wiley   +1 more source

Harnessing Bifunctional N‐Benzoyloxyamides for Photoredox Amidative Dual Functionalizations of Alkenes

Angewandte Chemie, EarlyView.
A novel photocatalytic strategy is presented for intermolecular amidative dual functionalization of alkenes using N‐benzoyloxyamides as bifunctional N─O reagents. The method enables efficient olefin 1,2‐amidooxygenation and significantly extends its reactivity to encompass amidoazidation, diamination, and formal anti‐Markovnikov hydroamidation.
Harin Ryoo, Hyeyun Keum, Dongwook Kim, Sukbok Chang   +3 more
wiley   +2 more sources

Contamination of agricultural products with pesticide residues in the period 1996 – 1998 – comparison with the period 1987 – 1995

Acta Agriculturae Slovenica, 2000
In the period 1996 – 1998, 348 samples of different plants (potato, grapes, maize, apples, carrots, lettuce, cabbage) were collected directly from their growth places.
Gregor UREK, Ana GREGORČIČ
doaj   +1 more source

Peroxide‐Driven Nitrogen Fixation Reactions for Energy Storage Applications

Advanced Energy Materials, EarlyView.
Sustainable ammonia synthesis from air as a hydrogen energy carrier and storage medium is demonstrated via an efficient dual‐step electrochemical approach at ultralow overpotential (−0.1 V vs. RHE). Atmospheric nitrogen is first oxidized to nitrate using in situ generated peroxide, then directly converts to ammonia on the same electrode, achieving ...
James Ebenezer, Parthiban Velayudham, Alex Schechter   +2 more
wiley   +1 more source

Low‐Cost, High‐Efficiency Organic Solar Cells Based on Ecofriendly Processing Solvent

Advanced Energy and Sustainability Research, EarlyView.
A low‐complexity, cost‐effective donor material, PTQ10, combined with the high‐efficiency acceptor materials, BTP‐eC9 and Y6, demonstrates excellent performance with the ecofriendly solvent o‐xylene (XY) instead of the traditional chloroform (CF) for the spin‐coating method.
Yunpeng Qin, Haoran Tu, Nathan Woodward, Mihirsinh Chauhan, Gaurab J. Thapa, Aram Amassian, Justin Neuf, Wei You, Haipeng Yin, Harald Ade   +9 more
wiley   +1 more source

Computational screening of MXene-based catalysts for chlorinated hydrocarbons removal

JPhys Materials
Chlorinated hydrocarbons, widely used in industrial applications, pose significant environmental and health risks due to their persistence and toxicity. Conventional remediation methods often face efficiency limitations, necessitating the exploration of ...
Miroslav Kolos, František Karlický
doaj   +1 more source

Electrodialysis of LiPF6 in Aqueous Solution for Wastewater Treatment in Hydrometallurgical Recycling of Lithium‐Ion Batteries

Advanced Energy and Sustainability Research, EarlyView.
Hydrometallurgical recycling of lithium‐ion batteries produces wastewater containing PF6− and Li+, which must be removed and recovered, respectively. This study pioneers electrodialysis using anion exchange membrane and cation exchange membrane to separate PF6− and Li+.
Takuto Miyashita, Kouji Yasuda, Tetsuya Uda   +2 more
wiley   +1 more source

Chlorine‐dopant dynamically stabilizes Cu0/Cu+ active sites for selective CO2 electroreduction to multicarbon products

AIChE Journal, EarlyView.
Abstract The electrochemical CO2 reduction reaction (CO2RR) to multicarbon (C2+) products faces significant challenges rooted in the high energy barriers of C–C coupling, which can be addressed through dopant‐mediated stabilization of Cu+ species on Cu catalysts.
Congcong Li, Zhongyuan Guo, Jialin Cui, Tingting Zhang, Zhongliang Liu, Xiaoqing Mao, Yongjun Shen, Saiwu Yang, Yingfang Jiang, Pinghui Tang, Hao Li, Huihui Li, Chunzhong Li   +12 more
wiley   +1 more source

Environmental Behavior, Sources, and Effects of Chlorinated Polycyclic Aromatic Hydrocarbons

The Scientific World Journal, 2007
The environmental sources and behaviors of chlorinated 2- to 5-ring polycyclic aromatic hydrocarbons (ClPAHs). ClPAHs are ubiquitous contaminants found in urban air, vehicle exhaust gas, snow, tap water, and sediments.
Takeshi Ohura
doaj   +1 more source