Results 121 to 130 of about 70,987 (287)

Organocatalytic asymmetric fluorination of α-chloroaldehydes involving kinetic resolution

open access: yesBeilstein Journal of Organic Chemistry, 2014
In a previous study it was shown that the enantioselective α-fluorination of racemic α-chloroaldehydes with a chiral organocatalyst yielded the corresponding α-chloro-α-fluoroaldehydes with high enantioselectivity.
Kazutaka Shibatomi   +5 more
doaj   +1 more source

Intramolecular N···F Pnictogen Bond Mitigates the Explosive Behavior of Azido‐L‐Phenylalanines

open access: yesChemistryEurope, EarlyView.
An intramolecular N···F pnictogen bond is the key for the chemical stabilization of the fluorinated azido‐L‐phenylalanines, mitigating the risk of explosion and thus facilitating the handling and storage of these materials. Organic azides are versatile intermediates but are plagued by intrinsic instability and potential explosiveness. Here, it is shown
Andrea Pizzi   +5 more
wiley   +1 more source

Sensitivity Analysis of a Proposed Model for Removal Efficiency of Trihalomethanes (THMs) Using Spray Aeration [PDF]

open access: yes, 2013
Trihalomethanes (THMs) form in drinking water treatment systems as a byproduct of chlorination and are problematic from a public health perspective due to their carcinogenic potential and their potential for additional formation throughout distribution ...
Cecchetti, Aidan
core   +2 more sources

Research Progress on Halide Solid‐State Electrolytes: Synthesis, Mechanism, and Modification

open access: yesCarbon Energy, EarlyView.
This review comprehensively summarizes the research progress on halide solid‐state electrolytes, including their classifications, synthesis methods, ion conduction mechanisms, and modification strategies. It also proposes effective modification strategies to address critical issues, such as air stability and interface compatibility.
Weifeng Shen   +20 more
wiley   +1 more source

Direct Tungsten Extraction from Scheelite in a Molten Salt Media

open access: yesElectrochemistry
Tungsten is a basic metal commodity that is classified as critical raw material (CRM) by the European Commission (EC) with the highest economical importance compared to other CRM.
Ana Maria MARTINEZ   +2 more
doaj   +1 more source

Methyl on the Bridge: 2‐Methyl Propellane as Precursor for 1,3‐Substituted 2‐Methylated Bicyclo[1.1.1]Pentanes

open access: yesChemistry – A European Journal, EarlyView.
The synthesis of 2‐methyl propellane and its conversion to various 1,2‐ and 1,2,3‐di‐ and trisubstituted bicyclopentanes is reported. Abstract Bicyclo[1.1.1]pentanes (BCPs) have emerged as isosteric replacements for mono‐ and para‐substituted benzene rings in medicinal and materials applications, involving substitution at the BCP bridgehead (1,3 ...
Sean R. Verschaeve   +4 more
wiley   +1 more source

Full-length 16S rRNA gene sequencing reveals the operating mode and chlorination-aggravated SWRO biofouling at a nuclear power plant

open access: yesWater Science and Technology
Reverse osmosis (RO) membrane fouling and biological contamination problems faced by seawater desalination systems are microbiologically related. We used full-length 16S rRNA gene sequencing to assess the bacterial community structure and chlorine ...
Kaijia Ren   +5 more
doaj   +1 more source

Congener specific analysis of polychlorinated terphenyls [PDF]

open access: yes, 2010
In order to identify and to quantify polychlorinated terphenyls (PCT) in environmental matrices, the chro- matographic behavior of coplanar and non-coplanar congeners was evaluated.
Bahadir, M.   +4 more
core  

Tuning the Twist by Molecular Design: A New Strategy for Hexabenzocoronene‐Containing Helical Twistacene

open access: yesChemistry – A European Journal, EarlyView.
An efficient Scholl–based strategy enables precise control of the C–C bond to access the first hexabenzocoronene–containing helical twistacene (NG2). The resulting nanographene shows pronounced helical distortion, high stability, enhanced solubility, and promising redox and optoelectronic properties.
Juan P. Mora‐Fuentes   +8 more
wiley   +1 more source

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