Results 131 to 140 of about 44,999 (295)
ChemistryEurope, EarlyView.Reacting 1‐hydridosilatrane with triphenylcarbenium hexachloridoantimonate in acetonitrile solution and in the presence of 4‐dimethylaminopyridine combines the world of silatranes with the world of carbenes, giving an unprecedented carbene‐type antimony pentachloride complex. This finding offers a new playground for exciting new chemistry.
David Mroß +7 more
wiley +1 more source
Evidences of the Stabilization for Weeks of the Benzyl Cation in Zeolites
ChemistryEurope, EarlyView.The benzyl cation is plausibly formed inside zeolites after rearrangement of individually isolated tropylium cations at room temperature. The benzyl cation–entrapped zeolite is stable for weeks without any storage precaution, and a solid–state 13C nuclear magnetic resonance spectrum of this iconic carbocation could be recorded.
Francesco Orlando +3 more
wiley +1 more source
ChemistryEurope, EarlyView.From axial and peripheral reactivity to remote derivatization, the chemical versatility of subphthalocyanines (SubPcs) renders them ideal scaffolds for the design of advanced functional materials. This review assembles the synthetic toolbox, key reaction conditions, and future challenges in SubPc functionalization, guiding the development of next ...
Marta Gómez‐Gómez +4 more
wiley +1 more source
Two-step coupled photoelectrochemical chlorination and oxygenation of C(sp<sup>3</sup>)-H bonds mediated by chlorine radicals over a modified BiVO<sub>4</sub> photoanode. [PDF]
Chem SciYang W +8 more
europepmc +1 more source
ChemistryEurope, EarlyView.Ring‐opening metathesis polymerization offers access to borane polymers with tunable Lewis acidity, environmental stability, and luminescence. The Lewis acid strength approaches that of B(C6F5)3 when R = Cl and Ar = C6F5, high stability is ensured with chlorophenyl or naphthyl pendent groups (Ar = ClPh, Np), and strong emission is achieved with a ...
James McQuade +5 more
wiley +1 more source