Triplet 4‐Nitrenemethyl‐Pyridine‐N‐Oxide: A Model Alkyl Nitrene Isolated in Cryogenic Matrices
The simplest triplet alkyl nitrene bearing a pyridine‐N‐oxide moiety was generated by direct irradiation (λ > 350 nm) of the corresponding azide in an Ar matrix at 15 K. Quantum tunneling 1,2‐H shift to the corresponding imine is thermodynamically favorable but does not occur due to a high‐energy barrier (~36 kcal mol−1).
Cláudio M. Nunes +5 more
wiley +1 more source
Electrochemical Halogenation and Etherification of Alcohols Enabled by a Halide-Coupled Phosphine Oxidation. [PDF]
Hale EA, Ngo VT, Zhu Q.
europepmc +1 more source
ABSTRACT Rationale Estrogen‐related receptor (ERR) agonists such as the drug candidates SLU‐PP‐332 and SLU‐PP‐915 are currently being investigated as exercise mimetics, given their ability to trigger human physiological processes similar to those initiated by actual physical activity.
Tristan Möller +2 more
wiley +1 more source
Comparison of electro-oxidation coupled with UV irradiation (UV/EO) <i>versus</i> conventional oxidation processes (UV irradiation, chlorination, electro-oxidation, and UV/chlorine) for atenolol removal: role of operating parameters, energy performance, and toxicity. [PDF]
Duangkaew P, Phattarapattamawong S.
europepmc +1 more source
From Hemp Bast to Lyocell Fiber: Sustainable Process Optimization for Lyocell‐Grade Dissolving Pulp
This study presents a sustainable method to produce lyocell‐grade dissolving pulp from Canadian hemp bast fibers. A simplified alkali‐chelation‐bleaching process, free from sulfur and chlorine, yielded high α‐cellulose pulp with low lignin and hemicellulose content. The pulp was successfully spun into continuous hemp‐based lyocell fibers, demonstrating
Md Abu Sayed +8 more
wiley +1 more source
Making Blank Faces Expressive: Chemical Approaches to the Modification of Chemically Inert Peptides. [PDF]
Moriyama Y, Sada H, Nanjo T.
europepmc +1 more source
Divergent Access to Fluorinated Pharmacons From Ethyl Trifluoropyruvate
Fluoro(oxo) functional group diversification is traditionally accomplished through either specialized reagents or nucleophilic trifluoromethylation. Herein is disclosed the use of commercially available building blocks for the synthesis of trifluoromethyl(hydroxy) esters.
Rifat N. Nabi +4 more
wiley +1 more source
Reactivity umpolung of the cycloheptatriene core in hexa(methoxycarbonyl)cycloheptatriene. [PDF]
Platonov DN +4 more
europepmc +1 more source
ABSTRACT Mussel aquaculture depends on a consistent spat supply, often sourced from spat‐collection ropes suspended in coastal waters. However, settlement on these ropes can be highly variable due to environmental factors. Therefore, improving spat supply from this source relies on optimising aspects of the process, particularly the timing of ...
Kayleb Himiona +2 more
wiley +1 more source

