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The Impact of pH and Irradiation Wavelength on the Production of Reactive Oxidants during Chlorine Photolysis.

Environmental Science and Technology, 2019
Chlorine photolysis is an advanced oxidation process which relies on photolytic cleavage of free available chlorine (i.e., hypochlorous acid and hypochlorite) to generate hydroxyl radical, along with ozone and a suite of halogen radicals. Little is known
Devon Manley Bulman   +2 more
semanticscholar   +1 more source

Selectivity between Oxygen and Chlorine Evolution in the Chlor-Alkali and Chlorate Processes.

Chemical Reviews, 2016
Chlorine gas and sodium chlorate are two base chemicals produced through electrolysis of sodium chloride brine which find uses in many areas of industrial chemistry.
Rasmus Karlsson, A. Cornell
semanticscholar   +1 more source

Comparing the UV/Monochloramine and UV/Free Chlorine Advanced Oxidation Processes (AOPs) to the UV/Hydrogen Peroxide AOP Under Scenarios Relevant to Potable Reuse.

Environmental Science and Technology, 2017
Utilities incorporating the potable reuse of municipal wastewater are interested in converting from the UV/H2O2 to the UV/free chlorine advanced oxidation process (AOP).
Y. Chuang   +3 more
semanticscholar   +1 more source

The Multiple Role of Bromide Ion in PPCPs Degradation under UV/Chlorine Treatment.

Environmental Science and Technology, 2018
This study investigated the role of bromide ions in the degradation of nine pharmaceuticals and personal care products (PPCPs) during the UV/chlorine treatment of simulated drinking water containing 2.5 mgC L-1 natural organic matter (NOM).
Shuangshuang Cheng   +6 more
semanticscholar   +1 more source

Autocatalytic Decomplexation of Cu(II)-EDTA and Simultaneous Removal of Aqueous Cu(II) by UV/Chlorine.

Environmental Science and Technology, 2019
Traditional processes usually cannot enable efficient water decontamination from toxic heavy metals complexed with organic ligands. Herein, we first reported the removal of Cu(II)-EDTA by a UV/chlorine process, where the Cu(II)-EDTA degradation obeyed ...
Xianfeng Huang   +8 more
semanticscholar   +1 more source

Achieving high open-circuit voltage on planar perovskite solar cells via chlorine doped tin oxide electron transport layers.

ACS Applied Materials and Interfaces, 2019
The open-circuit voltage deficit is one of the main limiting factors for the further performance improvement in planar structured perovskite solar cells. In this work, we elaborately develop chlorine binding on the surface of tin oxide electron transport
Jiwei Liang   +6 more
semanticscholar   +1 more source

Reactivity of Enveloped Virus Genome, Proteins, and Lipids with Free Chlorine and UV254.

Environmental Science and Technology, 2018
The survivability of viruses in natural and engineered systems impacts public health. Inactivation mechanisms in the environment have been described for nonenveloped viruses, but it remains unclear how the membrane layer of enveloped viruses influences ...
Yinyin Ye   +3 more
semanticscholar   +1 more source

The roles of reactive species in micropollutant degradation in the UV/free chlorine system.

Environmental Science and Technology, 2014
The UV/free chlorine process forms reactive species such as hydroxyl radicals (HO(•)), chlorine atoms (Cl(•)), Cl2(•-), and O(•-). The specific roles of these reactive species in aqueous micropollutant degradation in the UV/chlorine process under ...
Jingyun Fang, Yun Fu, C. Shang
semanticscholar   +1 more source

Hydrogen Atom Transfer Reactions via Photoredox Catalyzed Chlorine Atom Generation.

Angewandte Chemie, 2018
The selective functionalization of chemically inert C-H bonds remains to be fully realized in achieving organic transformations that are redox-neutral, waste-limiting, and atom-economical.
S. Rohe   +3 more
semanticscholar   +1 more source

Synthesis of Chlorine-Substituted Graphdiyne and Applications for Lithium-Ion Storage.

Angewandte Chemie, 2017
Chlorine-substituted graphdiyne (Cl-GDY) is prepared through a Glaser-Hay coupling reaction on the copper foil. Cl-GDY is endowed with a unique π-conjugated carbon skeleton with expanded pore size in two dimensions, having graphdiyne-like sp- and sp2 ...
Ning Wang   +10 more
semanticscholar   +1 more source

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