Hydrazine Synthase From Anammox Is Inhibited by Linear and Aromatic Alkynes
Linear and aromatic alkynes inhibit anammox in culture and in wetlands. The inhibition by alkynes is specific to the hydrazine synthase, a key enzyme in the anammox pathway. ABSTRACT N2O emissions by nitrifiers are often estimated using selective inhibitors, such as 1‐alkynes.
Cerys Maryan +7 more
wiley +1 more source
Insight into Solvent Coordination of an Iron Porphyrin Hydroxylamine Complex from Spectroscopy and DFT Calculations [PDF]
The reduction of Fe(OEP)(NO) in the presence of substituted phenols leads to a three‐electron reduction to form Fe(OEP)(NH2OH), which has been characterized by visible spectroscopy and electron stoichiometry.
Rahman, Md. Hafizur, Ryan, Michael D.
core +2 more sources
Integrated machine learning framework for phenolic derivatives: classification (toxicity) and regression (logP) models identify top drug‐like compounds. Random Forest outperformed for toxicity, while Linear Regression best predicted logP. A weighted scoring approach prioritized five safe, lipophilicity‐optimized candidates, supporting rational ...
Houria Nacer +7 more
wiley +1 more source
A molecular defect‐mediated charge accumulation strategy is developed to regulate the exciton behavior for selective molecular oxygen (O2)activation in poly(1,3,5‐triethynylbenzene) (PTEB). Artificial internal electric field (IEF) constructed in defective PTEB provides internal driving force to steer the directed migration of charge carriers, thereby ...
Xiaofeng Tang +8 more
wiley +1 more source
Oxidation-Reduction Characteristics of Chlorophenols in an Aprotic Medium [PDF]
Eighteen chlorophenols, containing from one to five chlorine atoms on the benzene ring at various positions, have been studied by cyclic voltammetric methods to evaluate their oxidation-reduction characteristics in an aprotic medium.
Samokyszyn, Victor M. +2 more
core +1 more source
Effects of dissolved oxygen, pH, and anions on the 2,3-dichlorophenol degradation by photocatalytic reaction with anodic TiO?nanotube films [PDF]
2008-2009 > Academic research: refereed > Publication in refereed journalAccepted ...
Li, XZ, Liang, HC, Sze, KH, Yang, YH
core +1 more source
This study develops a phosphorus‐doped cobalt single‐atom catalyst that enhances high‐valent cobalt–oxo species generation for water purification. This atomic‐level tuning boosts the catalyst's activity by 3.5 times, enabling efficient pollutant degradation. A continuous‐flow reactor achieves high, long‐term removal efficiency, producing water with low
Wen‐Min Wang +4 more
wiley +1 more source
A Multipronged Comparative Study of the Ultraviolet Photochemistry of 2-, 3-, and 4-Chlorophenol in the Gas Phase [PDF]
The S1(1ππ*) state of the (dominant) syn-conformer of 2-chlorophenol (2-ClPhOH) in the gas phase has a subpicosecond lifetime, whereas the corresponding S1 states of 3- and 4-ClPhOH have lifetimes that are, respectively, ∼2 and ∼3-orders of magnitude ...
Ashfold, M N R +16 more
core +3 more sources
Influence of activated carbons on the kinetics and mechanisms of aromatic molecules ozonation [PDF]
Companies have been looking for new methods for treating toxic or refractory wastewaters; which can mainly be used prior to or after or in connexion with biological treatment processes.This paper compares conventional ozone oxidation with activatedcarbon
Debellefontaine, Hubert +4 more
core +2 more sources
New branches in the degradation pathway of monochlorocatechols by Aspergillus nidulans: a metabolomics analysis [PDF]
A collective view of the degradation of monochlorocatechols in fungi is yet to be attained, though these compounds are recognised as key degradation intermediates of numerous chlorinated aromatic hydrocarbons, including monochlorophenols.
Galcerán Huguet, M. Teresa +5 more
core +1 more source

