Results 151 to 160 of about 250,341 (305)

Asymmetric Reduction of Unactivated Alkenes

open access: yesChemistry – A European Journal, EarlyView.
Unactivated alkenes rank among the most inert functional groups in synthesis and their selective reduction remains challenging. This Review charts the evolution from classical metal‐catalyzed hydrogenation to radical hydrogen atom transfer (HAT) and emerging biocatalytic concepts, highlighting how complementary mechanistic strategies, including the ...
Nico D. Fessner   +3 more
wiley   +1 more source

Mimicking The Photosynthetic Special Pair With Aluminum(III) Porphyrin Homodimer – Fullerene (C60) Supramolecular Assemblies Capable of Long‐Lived Charge Separation

open access: yesChemistry – A European Journal, EarlyView.
The axial‐bonding of aluminum(III) porphyrins was used to create two covalently linked special‐pair mimics to probe charge‐transfer between a porphyrin dimer and a C60 unit for artificial photosynthesis. Although excitonic coupling between the porphyrins is weak, incorporation of a second porphyrin markedly increases both the yield and lifetime of the ...
Stefan Charon   +7 more
wiley   +1 more source

Optimization of a reactor for biostimulant production with emphasis on the economic aspects of hydrolysis

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract Biostimulants are increasingly used in agriculture to promote plant growth, improve stress tolerance, and support sustainable farming practices. One common method of production is chemical hydrolysis of protein‐rich waste, such as tannery by‐products, offering an economical and eco‐friendly alternative to conventional raw materials.
Karel Kolomazník   +3 more
wiley   +1 more source

Green Chemistry im Chemieunterricht: eine farbstoffsensibilisierte Solarzelle mit sicheren und leicht verfügbaren Materialien

open access: yesCHEMKON, EarlyView.
Farbstoffsensibilisierte Solarzellen (Dye‐sensitized Solar Cells, DSSCs) stellen einen biomimetischen Ansatz zur Umwandlung von Sonnenlicht in elektrische Energie dar, der sich am Funktionsprinzip der Photosynthese orientiert. Trotz ihres seit den frühen 1990er‐Jahren bekannten Konzepts existieren bislang nur wenige experimentelle Zugänge, die zugleich
Kristin Sellmann   +3 more
wiley   +1 more source

Latent Dirichlet Allocation Uncovers Spectral Characteristics of Drought Stressed Plants

open access: yes, 2012
Understanding the adaptation process of plants to drought stress is essential in improving management practices, breeding strategies as well as engineering viable crops for a sustainable agriculture in the coming decades.
Ballvora, Agim   +8 more
core  

High atmospheric pressure rescues plant growth under humidity stress: A model for climate‐resilient deep underground agriculture

open access: yesDeep Underground Science and Engineering, EarlyView.
High atmospheric pressure (120 kPa) in deep underground counteracts humidity‐induced physiological stress in plants, stabilizing water balance and enhancing antioxidative defenses. This synergy boosts biomass despite elevated humidity, demonstrating sustainable deep underground agriculture potential under climate uncertainty.
Yuxin He   +6 more
wiley   +1 more source

Natural Anthraquinone‐Like Compound Extracted from Green Husk of Walnut Improves Photocatalytic H2O2 Production Catalyzed by TiO2 Nanoparticles

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
In this work, a novel biomolecule/semiconductor hybrid catalyst was prepared by loading anthraquinone‐liked juglone onto anatase TiO2. This catalyst exhibited high photocatalytic activity for H2O2 production. Hydrogen peroxide (H2O2) is a vital oxidant with broad industrial applications, and its production via photocatalysis represents a highly ...
Zengyin He   +4 more
wiley   +1 more source

Ground‐ and Excited‐State Mixed Valency in a 4,4′‐Bipyridine‐Bridged Bimetallic Di‐Ruthenium Complex

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Photoinduced mixed‐valence interactions across a 4,4′‐bpy bridge were studied. MLCT excited states in the bimetallic complex are longer‐lived than in the monometallic reference, thanks to metal–metal electronic coupling and hole delocalization, but are still shorter than the nanosecond timescale relevant for diffusional reactivity.
Ivana Ramírez‐Wierzbicki   +3 more
wiley   +1 more source

1,1‐Disubstituted Vinylbromides: Versatile Building Blocks for the Synthesis of Nitrogen‐Containing Heterocycles

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
1,1‐Disubstituted vinylbromides are key intermediates for constructing nitrogen‐containing heterocycles. This review provides an overview of the synthetic applications of 1,1‐disubstituted vinylbromides and summarizes recent developments in reaction methodologies, mechanistic insights, and the structural diversity of N‐heterocyclic compounds accessible
Anne Westermeyer   +6 more
wiley   +1 more source

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