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Kinetics of thermal interconversion between cis,cis-1,3,5-octatriene, cis,cis,cis-2,4,6-octatriene, and cis,cis,trans-2,4,6-octatriene

The Journal of Organic Chemistry, 1988
L'isomerisation entre le cis,cis,cis- et le cis,cis,trans-octatriene-2,4,6 se fait de maniere indirecte en passant par l'intermediaire cis,cis-octatriene-1,3,5 mais aussi de maniere ...
John E. Baldwin, V. Prakash Reddy
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cis,cis,cis,cis-1,2,3,4,5-Pentakis(hydroxymethyl)cyclopentane

The Journal of Organic Chemistry, 1985
Synthese du compose du titre par addition de Diels Alder de l'anhydride maleique avec le benzyloxymethyl ...
Laren M. Tolbert   +2 more
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The inversion of cis-transoid-cis- and cis-cisoid-cis-perhydroanthracene

Tetrahedron Letters, 1982
Abstract The factor responsible for the difference between the inversion barriers of cis-transoid-cis- and cis-cisoid-cis -perhydroanthracene were explored by molecular mechanics.
P. Vanhee   +3 more
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All-cis-retinal and 7-cis,9-cis,11-cis-retinal1

Tetrahedron Letters, 1988
Abstract A modified 15 + 5 route led to 7- cis ,9- cis ,11- cis -retinonitrile in high selectivity and also a lesser amount of all- cis -retinonitrile. DIBAL reduction gave the corresponding retinal isomers. The absorption maximum 287nm of all- cis -retinal reveals the distorted nature of the chromophore.
Achla Trehan, R.S.H. Liu
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Enantioselective syntheses of cis, syn, cis- and cis, anti, cis-linear triquinanes

Tetrahedron: Asymmetry, 2008
Enantioselective syntheses of both cis, syn, cis- and cis, anti, cis-linear triquinanes, starting from the readily available (S)-campholenaldehyde, employing an RCM reaction-based cyclopentannulation strategy, are described.
Srikrishna, Adusumilli, Beeraiah, Baire
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ChemInform Abstract: CIS,CIS,CIS,CIS‐1,2,3,4,5‐PENTAKIS(HYDROXYMETHYL)CYCLOPENTANE

Chemischer Informationsdienst, 1985
AbstractDie Synthese des im Titel genannten Cyclopentans (V) gelingt durch Diels‐Alder‐Addition.
L. M. TOLBERT   +2 more
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A cis,trans,cis,cis-[4.5.5.5]Fenestrane Derivative

Acta Crystallographica Section C Crystal Structure Communications, 1996
The title compound, rel-(1R,4R,7S,10R)-7-(tert-butyldimethylsilyloxy)tetracyclo [5.4.1.04,12.010,12]dodecan-2-one, C18H30O2Si, has been prepared and its structure determined. The geometry of the central C(C)4 substructure of the fenestrane skeleton shows a considerable distortion from an ideal tetra­hedral arrangement towards planarity. Values of 127.0 
M. Thommen, R. Keese, M. Förtsch
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A Substituted cis,trans,cis,cis-[4.5.5.5]Fenestrene

Acta Crystallographica Section C Crystal Structure Communications, 1996
The title compound, rel-(1S,4R,7R,9S-tetracyclo- [5.4.1.0 4,12 .0 9,12 ]dodec-10-enyl-l-acetic acid, C 14 H 18 O 2 , has been prepared and its structure elucidated. The geometry of the central C(C)4 substructure shows a considerable distortion from an ideal tetrahedral arrangement towards planarity, with two opposite bond angles of of 119.2(2) and 134 ...
J. Wang, M. Thommen, R. Keese
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Mass Spectrometry Used to Discriminate Between Cis‐Syn‐Cis and Cis‐Anti‐Cis Photoadducts

Bulletin des Sociétés Chimiques Belges, 1980
AbstractCis‐syn‐cis and cis‐anti‐cis regioisomers of tricyclo [6.2.0.02, 7] decan‐3‐ones or tricyclo [5.2.0.02, 6nonan‐3‐ones, formed by (π2 +π2) photocycloaddition reactions between 1, 2‐bis (trimethylsiloxy) cyclobutene and 2‐cyclohexenones or 2‐cyclopentenones, respectively, are unequivocally identified by analysis of the isobutane chemical ...
Martine Van Audenhove   +2 more
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cis,cis,cis-Tetramethyl 1,2,4,5-cyclohexanetetracarboxylate

Acta Crystallographica Section C Crystal Structure Communications, 2000
The title compound, C(14)H(20)O(8), was synthesized from the hydrogenation of tetramethyl 1,4-cyclohexadiene-1,2,4, 5-tetracarboxylate with a catalytic amount of palladium/carbon. All four carbonyl moieties of the methyl ester groups are on the same face of the chair-conformed ring.
, Robinson   +6 more
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