Results 131 to 140 of about 43,635 (227)

Injectable Bone Cements: A Generational Framework for Bioactivity, Porosity, and Mechanobiological Design at the Nanoscale

open access: yesAdvanced NanoBiomed Research, EarlyView.
Key demographic, biological, and material considerations that drive the need for advanced injectable bone cement technologies. Injectable bone cements (IBCs) are widely used in orthopaedic and craniofacial applications due to their minimally invasive delivery and ability to provide early mechanical stabilisation.
Frank Fei   +2 more
wiley   +1 more source

Cobalt‐Catalyzed Intramolecular C─H Silylation of Arenes

open access: yesAngewandte Chemie, EarlyView.
Direct C─Si bond formation via C─H silylation is an atom‐economical route to organosilanes but is largely limited to noble metals. We report the first cobalt‐catalyzed intramolecular arene C–H silylation enabled by HCo(PMe3)4, which activates Si–H and C–H bonds to form diverse silacycles and silafluorenes in high yields with broad functional‐group ...
Yongqiang Xu   +4 more
wiley   +2 more sources

NiH‐Catalyzed Enantioconvergent α‐Alkenylation of Carbonyl Compounds via Markovnikov Alkyne Hydronickellation

open access: yesAngewandte Chemie, EarlyView.
A NiH‐catalyzed α‐alkenylation via Markovnikov hydronickellation of alkynes enables convenient access to α‐chrial β‐methylene carbonyl frameworks that are prevalent in biorelevant molecules. High regio‐ and enantioselectivities have been achieved with excellent functional group tolerance and applicability toward complex structures. The β‐methylene unit
Hyeontaek Nam   +3 more
wiley   +2 more sources

Cobalt-catalyzed alkyne silylamidation unlocks <i>Z</i>-selective unnatural dehydropeptides synthesis. [PDF]

open access: yesNatl Sci Rev
Wang J   +9 more
europepmc   +1 more source

Convergent Valorization via Scalable C═N Bond Electrosynthesis Through Metal‐Dopant Interfacial Engineering in a Flow Electrolyzer

open access: yesAngewandte Chemie, EarlyView.
This study establishes an innovative approach to synthesize organonitrogens featuring C═N bonds efficiently using non‐precious metal‐doped MoS2 in a flow electrolyzer. Fe dopant significantly enhances Faradaic efficiency and yield rate, achieving over 81% and 2630 mmol h−1 g−1 for formaldoxime production. This platform upcycles pollutants into valuable
Ruijie Yi   +9 more
wiley   +2 more sources

Couple-close: Unified approach to semisaturated cyclic scaffolds. [PDF]

open access: yesScience
Xie J   +9 more
europepmc   +1 more source

Co(II) Recovery from Hydrochloric Acid Solution Using Menthol-Based Deep Eutectic Solvents (DESs): Application to NMC Battery Recycling. [PDF]

open access: yesMolecules
Martín-Hernández MI   +6 more
europepmc   +1 more source

Metal Allergies in Total Shoulder Arthroplasty: A Scoping Review and Clinical Update. [PDF]

open access: yesJB JS Open Access
Haase LR   +5 more
europepmc   +1 more source

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