Results 91 to 100 of about 839,329 (389)

Cobalt-Porphyrin Catalyzed Electrochemical Reduction of Carbon Dioxide in Water II: Mechanism from First Principles

, 2010
We apply first principles computational techniques to analyze the two-electron, multi-step, electrochemical reduction of CO2 to CO in water using cobalt porphyrin as a catalyst.
Leung, Kevin, Medforth, Craig J., Nielsen, Ida M. B., Sai, Na, Shelnutt, J. A.   +4 more
core   +1 more source

Exploiting Two‐Photon Lithography, Deposition, and Processing to Realize Complex 3D Magnetic Nanostructures

Advanced Functional Materials, EarlyView.
Two‐photon lithography (TPL) enables 3D magnetic nanostructures with unmatched freedom in geometry and material choice. Advances in voxel control, deposition, and functionalization open pathways to artificial spin ices, racetracks, microrobots, and a number of additional technological applications.
Joseph Askey, Arjen van den Berg, Sandra Ruiz Gomez, Claire Donnelly, Dirk Grundler, Sam Ladak   +5 more
wiley   +1 more source

Dual‐Phased Molybdenum Carbides Confined in MOF‐Derived Carbon Nanoframes Enhance Capacitive Desalination

Advanced Functional Materials, EarlyView.
Dual‐phase MoC/Mo2C/CoNC nanoframes are synthesized via a MOF‐on‐MOF strategy, demonstrating a large salt adsorption capacity, a low energy consumption, and an excellent cycling stability. In situ/ex situ characterizations and DFT calculations reveal that the MoC/Mo2C dual phase transition facilitates Na+ adsorption/desorption, while interface‐induced ...
Feifei Pang, Bohan Liu, Jingyu Wu, Qian Yang, Zhichang Xiao, Ningzhao Shang, Xiaoxian Zhao, Yusuke Yamauchi, Shuaihua Zhang   +8 more
wiley   +1 more source

Intercalating cobalt between graphene and iridium (111): a spatially-dependent kinetics from the edges

, 2017
Using low-energy electron microscopy, we image in real time the intercalation of a cobalt monolayer between graphene and the (111) surface of iridium. Our measurements reveal that the edges of a graphene flake represent an energy barrier to intercalation.
Burgos, Benito Santos, Coraux, Johann, Kimouche, Amina, Locatelli, Andrea, Rougemaille, Nicolas, Vlaic, Sergio   +5 more
core   +3 more sources

Grain Boundary Space Charge Engineering of Solid Oxide Electrolytes: Model Thin Film Study

Advanced Functional Materials, EarlyView.
This study demonstrates unprecedented control of grain boundary electrical properties in solid electrolytes. Selective diffusion of cations through grain boundaries in thin films enables 12 orders of magnitude variation in ionic resistance, proving that systematic chemical modification of grain boundary electrical properties is feasible.
Thomas Defferriere, Yong Beom Kim, Colin Gilgenbach, James M. LeBeau, WooChul Jung, Harry L. Tuller   +5 more
wiley   +1 more source

Atomic cobalt on nitrogen-doped graphene for hydrogen generation

Nature Communications, 2015
Reduction of water to hydrogen through electrocatalysis holds great promise for clean energy, but its large-scale application relies on the development of inexpensive and efficient catalysts to replace precious platinum catalysts.
H. Fei, Juncai Dong, Josefina Arellano-Jiménez, Gonglan Ye, N. Kim, E. L. Samuel, Zhiwei Peng, Zhuan Zhu, F. Qin, J. Bao, M. Yacamán, P. Ajayan, Dongliang Chen, J. Tour   +13 more
semanticscholar   +1 more source

Inhibition of transition metals dissolution in cobalt-free cathode with ultrathin robust interphase in concentrated electrolyte

Nature Communications, 2020
The low Coulombic efficiency during cycling hinders the application of Cobalt-free lithium-rich materials in lithium-ion batteries. Here we demonstrated that the dissolution of iron, rather than traditionally acknowledged manganese, is mainly responsible
Wei Liu, Jinxing Li, Wenting Li, Hanying Xu, Chao Zhang, X. Qiu   +5 more
semanticscholar   +1 more source

Emergent Spin‐Glass Behavior in an Iron(II)‐Based Metal–Organic Framework Glass

Advanced Functional Materials, EarlyView.
A one‐pot, solvent‐free synthesis yields an Fe2+‐based metal‐organic framework (MOF) glass featuring a continuous random network structure. The material exhibits spin‐glass freezing at 14 K, driven by topological‐disorder and short‐range magnetic frustration, showcasing the potential of MOF glasses as a plattform for cooperative magnetic phenomena in ...
Chinmoy Das, Soma Salamon, Joachim Landers, Jan‐Benedikt Weiß, Wen‐Long Xue, Pascal Kolodzeiski, Roman Pallach, Heiko Wende, Sebastian Henke   +8 more
wiley   +1 more source

Electrochemical Formation of BiVO4/BiPO4 Photoanodes for Enhanced Selectivity toward H2O2 Generation

Advanced Functional Materials, EarlyView.
In acidic KPi, V dissolves from the BiVO4 lattice, while adsorbed phosphate reacts with the electrode under an external bias, forming a BiPO4 surface layer. This BiPO4 layer exhibits stronger bicarbonate adsorption, redirecting the water oxidation pathway toward two‐electron H2O2 production.
Kaijian Zhu, Xinyi Zhang, Lan Wen, Hongjiang Chen, Yudhistira Tirtayasri Amrillah, Vivi Fauzia, Hongzhen Dong, Shaoqiang Su, Wenjun Luo, Ferry Anggoro Ardy Nugroho, Patrick H.‐L. Sit, Yun Hau Ng, Fatwa F. Abdi   +12 more
wiley   +1 more source

Thermal-fatigue and oxidation resistance of cobalt-modified Udimet 700 alloy [PDF]

Comparative thermal-fatigue and oxidation resistances of cobalt-modified wrought Udimet 700 alloy (obtained by reducing the cobalt level by direct substitution of nickel) were determined from fluidized-bed tests.
Barrow, B. J., Bizon, P. T.
core   +1 more source