Results 251 to 260 of about 82,764 (294)
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Science, 2015
Electrochemistry Tethering molecular catalysts together is a tried and trusted method for making them easier to purify and reuse. Lin et al. now show that the assembly of a covalent organic framework (COF) structure can also improve fundamental catalytic performance. They used cobalt porphyrin complexes as building blocks for a COF.
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Electrochemistry Tethering molecular catalysts together is a tried and trusted method for making them easier to purify and reuse. Lin et al. now show that the assembly of a covalent organic framework (COF) structure can also improve fundamental catalytic performance. They used cobalt porphyrin complexes as building blocks for a COF.
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Cobalt Polyoxometalates as Heterogeneous Water Oxidation Catalysts
Inorganic Chemistry, 2013An insoluble salt of the water oxidation catalyst [Co9(H2O)6(OH)3(HPO4)2(PW9O34)3](16-) (Co9) has been used to modify amorphous carbon paste electrodes. The catalytic activity of this polyoxometalate is maintained in the solid state. Good catalytic rates are reached at reasonable overpotentials.
J. Soriano-López +5 more
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Cobalt selenium oxohalides: catalysts for water oxidation
Dalton Trans., 2014Two new oxohalides Co4Se3O9Cl2 and Co3Se4O10Cl2 have been synthesized by solid state reactions.
Faiz, Rabbani +8 more
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Hydroxyapatite supported cobalt catalysts for hydrogen generation
Journal of Colloid and Interface Science, 2013The controlled generation of H(2) from storage materials by using an efficient catalytic support is a highly sought after technology; however, the majority of successes utilize expensive materials considered unfeasible. In our report on the creation of a novel, durable, and inexpensive catalytic support material for hydrogen generation, we examine a ...
Justyn Wayne, Jaworski +6 more
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Cobalt species in promoted cobalt alumina-supported Fischer–Tropsch catalysts
Journal of Catalysis, 2007The structure of cobalt species at different stages of the genesis of monometallic and Pt-promoted cobalt alumina-supported Fischer–Tropsch catalysts was studied using X-ray diffraction, UV–visible spectroscopy, in situ X-ray absorption, in situ magnetic method, X-ray photoelectron spectroscopy, and DSC–TGA thermal analysis. The catalysts were prepared
W CHU +5 more
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Carbon monoxide hydrogenation on cobalt/alumina and cobalt/NaX catalysts
Applied Catalysis, 1991Abstract The synthesis of hydrocarbons from catalytic hydrogenation of carbon monoxide was investigated over Co/Al 2 O 3 and Co/NaX catalysts at 1 atm, 493–553 K, H 2 /CO = 2, and gas hourly space velocity (GHSV) = 1200. These catalysts were characterized by hydrogen chemisorption. X-ray diffraction (XRD), and temperature-programmed reduction.
Wei-Jye Wang, Yu-Wen Chen
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Sol?gel synthesis of cobalt?niobia catalysts
Solid State Ionics, 1997Cobalt-niobia catalysts were prepared using different variants of the colloidal sol-gel technique and wetness impregnation. Characterization of these catalysts by XRD, FT-IR, XPS and TEM showed that phases structure as well as superficial composition depended on the preparation route. It was found that niobia exhibits a strong metal support interaction
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CO2 hydrogenation over cobalt-containing catalysts
Kinetics and Catalysis, 2015Carbon dioxide hydrogenation over catalysts consisting of 0.56–45 wt % cobalt supported on carbon nanotubes (CNTs), carbon nanofibers, few-layer graphite fragments, or CNTs–Al2O3 composites has been investigated. All of the Co/support catalytic systems have been characterized by temperature-programmed reduction, transmission electron microscopy, and ...
E. V. Suslova +4 more
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Polymerization of isoprene with cobalt catalysts
Polymer Science Series B, 2014The polymerization of isoprene with catalytic systems efficient for the cis polymerization of butadiene, i.e., cobalt 2-ethyl hexanoate-diethylaluminum chloride and cobalt 2-ethyl hexanoate-ethylaluminum sesquichloride, is studied. The catalysts are obtained via in situ mixing of the components or at a reduced temperature (0–5°C) in the presence of a ...
V. A. Yakovlev +3 more
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Characterization of cobalt-impregnated VPO catalysts
Catalysis Today, 2000Abstract Cobalt-impregnated VPO catalysts containing 1–6% of the metal by weight were prepared. The catalytic tests showed that cobalt impregnation significantly increased the overall activity while slightly decreasing the maleic anhydride selectivity.
L.M. Cornaglia +3 more
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