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Cobalt(II) gluconate complexes

Australian Journal of Chemistry, 1970
A study of the cobalt(11) gluconate system has confirmed the existence of an unstable cationic species [Co(C6H1107)]+, in solutions of pH <7.5, and two insoluble compounds, CO2(OH)3(C6H11O7),xH2O and CO3(C6H10O7)2(OH)2,2H2O, formed in solutions of pH 7.5-9.5.
JF Ashton, WF Pickering
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Diazabutadiene cobalt(II) complexes

Transition Metal Chemistry, 1986
Studies on the chelates of cobalt(II) with the bidentate ligands 1,4-diphenyl(2,3-dimethyl-1,4-diazabutadiene) (PMB) and 1,4-di(p-methoxyphenyl)-2,3-dimethyl-1,4-diazabutadiene (MPMB) have been carried out. On the basis of elemental analyses, the complexes are [Co(PMB)Cl2], [Co(PMB)2(C1O4)2], [Co(MPMB)Cl2] and [Co(MPMB)2(ClO4)2].
Mar�a Jos� Camaz�n   +3 more
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NN-dialkylcarbamato-complexes of cobalt(II)

Journal of the Chemical Society, Dalton Transactions, 1984
By reaction of anhydrous cobalt(II) chloride with a secondary amine and carbon dioxide in a hydrocarbon solvent, NN-dialkylcarbamato-complexes of cobalt(II), [Con(O2CNR2)2n](R = Et or Pri), have been prepared. The crystal and molecular structure of the hexameric violet derivative, [Co6(O2CNEt2)12], has been solved by X-ray diffraction methods.
BELLI, DANIELA   +3 more
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Pyrazole complexes of cobalt(II)

Journal of the Chemical Society A: Inorganic, Physical, Theoretical, 1970
Cobalt acetylacetonates react with hydrazine hydrate in ethanolic solution to give bis-(3,5-dimethylpyrazolato)-cobalt(II). This and the corresponding salts of pyrazole and 3-methylpyrazole can also be prepared from cobalt(II) salts in basic solution. These compounds are believed to possess polymeric tetrahedral structures. In the absence of added base
M. J. Bagley   +2 more
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Zwitterionic complexes of cobalt(II)

Journal of the Chemical Society, Dalton Transactions, 1973
Pseudotetrahedral zwitterionic complexes of stoicheiometry [CoX3–L–L+], where X = Cl, Br, or I and L–L+ represents the cationic ligands Ph2PC2H4N(H)R2(R = H, Me, or Et) have been prepared by the reaction of L–LX– with CoX2. In the cases R = Me or Et, identical complexes were also prepared by the reaction of cobalt(II) halides with the unprotonated ...
R. A. Kolodny   +2 more
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Cobalt(II) complexes with hydantoin

Russian Journal of Inorganic Chemistry, 2008
Complexes of Co(II) with hydantoin (L, C3H4N2O2) have been synthesized. The complexes had the following compositions: [CoL2(OH2)2](NO3)2 · 2H2O, [CoL2(OH2)2]Cl2 · 3H2O, and [CoL2(OH2)2]SO4 · 2H2O. The individual character of the synthesized compounds are proved by the study of the IR absorption spectra (400–4000 cm−1) of all the compounds and the ...
L. N. Ambroladze   +2 more
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Low-spin cobalt(II) complexes. Part II. Cyanide complexes

Journal of the Chemical Society A: Inorganic, Physical, Theoretical, 1967
The complexes present in freshly-prepared solutions containing cobalt(II) and cyanide ions have been investigated. The main complex is identified as the hexaco-ordinate [Co(CN)5H2O]3– by comparison of its spectrum with those of the analogous isocyanide complexes.
J. M. Pratt, R. J. P. Williams
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Cobalt(II) Complexes of Isothiazole

Canadian Journal of Chemistry, 1971
The preparation and spectral properties are reported for complexes of CoX2 (X = Cl, Br, I) and Co(ClO4)2 with isothiazole (L). The following complexes have been prepared: CoL2X2, CoL4X2, and CoL6(ClO4)2. In the solid state, CoL2X2 (X = Br, Cl) are octahedral and polymeric, CoL4X2 (X = Br, Cl) are octahedral, CoL2I2 is tetrahedral, [CoL6](ClO4)2 is ...
R. Rivest, A. Weisz
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Cobalt(II) complexes of pyradine

Inorganica Chimica Acta, 1970
Abstract Pyridine complexes of cobalt(II) perchlorate, tetrafluoroborate, and nitrate have been prepared and studied by a variety of physical methods in both the solid and solution states. Their behavior is found to be generally similar to that of their nickel(II) analogues.
D.W. Herlocker, M.R. Rosenthal
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