Results 41 to 50 of about 801,196 (212)

Single‐Atom Cobalt Species on Curved Hollow Carbon Sphere: Breaking Linear Scaling Relationship Limitations in Electrocatalytic Deactivation of Dilute Antibiotic Pollutants

Advanced Science, EarlyView.
A cobalt (Co)‐SACs consisting of single‐atom Co anchored on a nitrogen‐doped hollow porous carbon sphere (Co1/N‐HCS) is fabricated for electrocatalytic hydrodechlorination of dilute antibiotics. The hollow porous architecture of N‐HCS concentrates the antibiotics, while its curved surface promotes proton transfer at the Co1 site via localized electric ...
Jiahong Zou, Shenbin Zheng, Chunyang Dan, Huimin Sui, Wenyang Fu, Xiaoshu Lv, Boping Ren, Guangming Jiang, Hong Liu   +8 more
wiley   +1 more source

Study of hyperfine interactions in spinel cobalt ferrite CoFe2O4 doped with Hf, Lu, and Yb using Mössbauer spectroscopy and perturbed γ-γ angular correlation

Конденсированные среды и межфазные границы
We studied hyperfine interactions (HFI) in spinel cobalt ferrite (ferrospinel) CoFe2O4 doped with Lu, Yb, and Hf (1 wt. %) by Mössbauer spectroscopy (MS) on 57Fe nuclei.
Viktor M. Vakhtel, Atanas I. Velichkov, Dimitar V. Karaivanov, Maria M. Milanova, Yuri G. Segal, Nargiza Temerbulatova, Dmitry V. Filosofov, Martin P. Tsvetkov   +7 more
doaj   +1 more source

Cobalt-Catalyzed Stereoretentive Hydrogen Isotope Exchange of C(sp³)–H Bonds [PDF]

ACS Catalysis, 2017
Cobalt dialkyl complexes bearing α-diimine ligands proved to be active precatalysts for the nondirected, C(sp3)-H selective hydrogen isotope exchange (HIE) of alkylarenes using D2 gas as the deuterium source. Alkylarenes with a variety of substitution patterns and heteroatom substituents on the arene ring were successfully labeled, enabling high levels
W. Neil Palmer, Paul J. Chirik
openaire   +2 more sources

Safety of Sodium‐Ion Batteries: Evaluation and Perspective from Component Materials to Cells, Modules, and Packs

Advanced Energy Materials, EarlyView.
This review provides a bottom‐up evaluation of sodium‐ion battery safety, linking material degradation mechanisms, cell engineering parameters, and module/pack assembly. It emphasizes that understanding intrinsic material stability and establishing coordinated engineering control across hierarchical levels are vital for preventing degradation coupling ...
Won‐Gwang Lim, Seoa Kim, Erik A. Wu, Darren H. S. Tan, Shawn Peng, Xiaolin Li   +5 more
wiley   +1 more source

Advancements in Graphdiyne‐Based Multiscale Catalysts for Green Hydrogen Energy Conversion

Advanced Intelligent Discovery, EarlyView.
This review systematically explores the fundamental characteristics of graphdiyne (GDY), cutting‐edge field of GDY‐based multiscale catalysts within sustainable energy conversion systems.Special emphasis is placed on the structure‒property relationships in different reactions.
Qian Xiao, Lu Qi, Siao Chen, Yurui Xue
wiley   +1 more source

Ligand architecture and secondary‐sphere effects in a well‐defined cobalt(IV)–oxo complex

Bulletin of the Korean Chemical Society, EarlyView.
A well‐defined cobalt(IV)–oxo complex supported by a neutral tetraazamacrocyclic ligand is generated and fully characterized. The cobalt(IV)–oxo species exhibits electrophilic oxygen‐atom and hydrogen‐atom transfer reactivity, strongly modulated by protonation and secondary coordination sphere effects, providing new insight into structure–reactivity ...
Ying Xing, Mi Sook Seo, Yong‐Min Lee, Wonwoo Nam   +3 more
wiley   +1 more source

Computational and Machine‐Learning Studies of Ethylene Oligomerization

Carbon and Hydrogen, EarlyView.
This review focuses on recent advances in computational and machine‐learning studies of ethylene oligomerization, highlighting mainstream catalyst systems based on Co, Ta, Ti, Zr, and Hf, with particular emphasis on Fe‐ and Cr‐based catalysts and their controlling factors governing reactivity and LAO distribution.
Zhixin Qin, Zhihui Song, Heying Feng, Li Jin   +3 more
wiley   +1 more source

The Newly Discovered Pathway for Oxygen Evolution Reaction: In‐Situ/Operando Characterization Techniques for Catalyst Development

Carbon Energy, EarlyView.
This study introduces a newly discovered oxide path mechanism (OPM) for the oxygen evolution reaction (OER), emphasizing the role of in‐situ and operando characterization techniques in unraveling catalyst behavior under realistic conditions. The integration of advanced spectroscopic methods provides new mechanistic insights for the design of highly ...
Rabia Khalid, Muhammad Tahir, Muhammad Umar, Pin Fang, Yujing Li   +4 more
wiley   +1 more source

Functionalizing Conductive Diamond: Recent Advance in Fabrication, Modifications, and Applications

Carbon Energy, EarlyView.
This review highlights recent advancements in the synthesis, modification, and electrochemical applications of conductive diamond, particularly boron‐doped diamond (BDD). It emphasizes progress in fabrication methods, including CVD and HPHT, and explores modifications such as doping, surface terminations, and composite design, enabling significant ...
Ning Linghu, Xin Jiang, Jing Xu
wiley   +1 more source

Spectroscopic Insights Into the Role of the Coverage of *CO and *H on Bifurcation of Ethylene and Ethanol Pathways in Carbon Dioxide Electroreduction

Carbon Energy, EarlyView.
Zhao et al. control the coverage of *CO or *H intermediates by introducing foreign metal into Cu nanoparticles. The increased *CO coverage on Ag‐doped and Zn‐doped Cu promotes the generation of multi‐carbon products while the increased *H coverage of Co‐doped and Pd‐doped Cu enhances the selectivity of oxygenates. ABSTRACT As key reaction intermediates
Zi‐Hao Zhao, Wenchao Liu, Zhan Liu, Dan Ren   +3 more
wiley   +1 more source