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Polycarbazole–NiOOH Interfacial Engineering of BiVO4 Photoanodes for Efficient and Stable Solar Water Splitting

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A π‐conjugated carbazole (p‐CBZ) layer is electro‐polymerized on BiVO4 to form a p–n heterojunction that enhances charge separation and suppresses surface recombination, while a NiOOH co‐catalyst accelerates oxygen evolution kinetics. The synergistic BVO/p‐CBZ/NiOOH photoanode delivers a high photocurrent density and long‐term stability for efficient ...
Lakshman Sundar Arumugam   +11 more
wiley   +1 more source

Doped Ta3N5 Semi‐Transparent Photoanode Enabling Stable Solar Redox Flow Cell Operation

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Synergistic Al:TiO2 underlayer and La doping stabilize semitransparent Ta3N5 photoelectrodes for over 90 h of continuous operation in alkaline solution. The solar redox flow cell demonstrated 12 photocharge–discharge cycles at ∼55% coulombic efficiency using a K4Fe(CN)6|1,5‐DHAQ chemistry. Solar redox flow cells (SRFCs) are photoelectrochemical devices
Filipe Moisés M. Francisco   +4 more
wiley   +1 more source

A High‐Performance Oxidized Graphene for Dendrite‐Free Anodes and Kinetically Enhanced Cathodes of Aqueous Zn‐Ion Batteries

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Oxidized graphene rich in carboxylic acid groups obtained via a simple electrochemical exfoliation route is shown to tackle the main challenges of aqueous Zn‐ion batteries (AZIBs), specifically short Zn anode cycle life and sluggish cathode reaction kinetics.
Enrique Álvarez‐Rubiera   +9 more
wiley   +1 more source

Harnessing Thin‐Film Solid‐State Electrolytes: Enabling Breakthroughs in All‐Solid‐State Batteries

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Schematic illustration highlighting the advantages of transitioning from traditional thick solid‐state electrolytes (SSEs) to thin‐film SSEs. Thinning the electrolyte enables higher ionic conductivity, reduced interfacial polarization, improved flexibility, compact electrode contact, and enhanced energy density, offering a promising pathway toward high‐
Yitao He   +3 more
wiley   +1 more source

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