Results 111 to 120 of about 26,716 (284)

Thermodynamic Studies of [H_(2)Rh(diphosphine)_2]^+ and [HRh(diphosphine)_(2)(CH_(3)CN)]^(2+) Complexes in Acetonitrile [PDF]

, 2010
Thermodynamic studies of a series of [H_(2)Rh(PP)_2]^+ and [HRh(PP)_(2)(CH_(3)CN)]^(2+) complexes have been carried out in acetonitrile. Seven different diphosphine (PP) ligands were selected to allow variation of the electronic properties of the ligand ...
Bercaw, John E., DuBois, Daniel L., Labinger, Jay A., Miller, Alexander J. M., Wilson, Aaron D.   +4 more
core   +1 more source

A Paramagnetic Nickel–Zinc Hydride Complex

Angewandte Chemie
AbstractReaction of a molecular zinc–hydride [{(ArNCMe)2CH}ZnH] (Ar=2,6‐di‐isopropylphenyl) with 0.5 equiv. of [Ni(CO)Cp]2 led to the isolation of a nickel–zinc hydride complex containing a bridging 3‐centre,2‐electron Ni−H−Zn interaction. This species has been characterized in the solid‐state by single crystal X‐ray diffraction.
Marina Perez‐Jimenez, Blaise L. Geoghegan, Alberto Collauto, Maxie M. Rößler, Mark R. Crimmin   +4 more
openaire   +3 more sources

Synthesis and characterization of Magnesium-Iron-Cobalt complex hydrides. [PDF]

Sci Rep, 2020
Barale J, Deledda S, Dematteis EM, Sørby MH, Baricco M, Hauback BC.   +5 more
europepmc   +1 more source

Combined Effects of Anion Substitution and Nanoconfinement on the Ionic Conductivity of Li-Based Complex Hydrides. [PDF]

J Phys Chem C Nanomater Interfaces, 2020
Zettl R, de Kort L, Gombotz M, Wilkening HMR, de Jongh PE, Ngene P.   +5 more
europepmc   +1 more source

Editorial: Metal Hydride-Based Energy Storage and Conversion Materials

Frontiers in Chemistry, 2020
Yongfeng Liu, Hai-Wen Li, Zhenguo Huang
doaj   +1 more source

Molecular Mimics of Intermetallic Phases: Selective Alkylamide‐Ligand Deprotection Drives Co/Ga Cluster Formation

Angewandte Chemie International Edition, EarlyView.
The bimetallic M14 cluster [Co3Ga2]H(μ2‐GaTMP)9 was achieved by a co‐reductive approach utilizing Mg and H2 to selectively deprotect and capture the Ga‐TMP metallo‐ligands, forming a Co/Ga alloyed cluster kernel, making it a structural representative of a related solid‐state counterpart.
Fabrizio E. Napoli, Raphael Bühler, Johannes Stephan, Samia Kahlal, Jean‐Yves Saillard, Christian Gemel, Roland A. Fischer   +6 more
wiley   +1 more source

Structural, electronic, optical and elastic properties of Mg3TH7 (T=Mn, Tc and Re) complex hydrides: First-principles calculations

Revue des Énergies Renouvelables, 2015
The structural, electronic, optical and elastic properties of Mg3TH7 (T=Mn, Tc, Re) complex hydrides have been investigated by using the density functional theory ‘DFT’ within the generalized gradient approximation ‘GGA’ parameterized by the Perdew ...
K. Benyelloul, Y. Bouhadda, M. Bououdina, N. Fenineche, H. Aourag, H. Faraoun   +5 more
doaj  

Hydrogen Storage Materials: Promising Materials for Kazakhstan’s Hydrogen Storage Industry

Eurasian Chemico-Technological Journal
Hydrogen, widely recognized as an efficient and clean energy carrier, holds significant promise for transforming future energy systems. Despite advances in hydrogen production and cost reduction, challenges in hydrogen storage continue to impede its ...
S. Abdimomyn, S. Malik, M. Skakov, Y. Koyanbayev, A. Miniyazov, F. Malchik   +5 more
doaj   +1 more source

Leveraging Atomic Disorder to Modulate Hydrogen Storage Thermodynamics in Intermetallics

Interdisciplinary Materials
Hydrogen storage in metal hydrides holds great promise for advancing a low‐carbon energy future. Yet, fine‐tuning the thermodynamics of hydrogen absorption remains challenging with traditional microalloying approaches. Here, we report a strategy inspired
Yuanyuan Shang, Ting Chen, Zhifeng Lei, Archa Santhosh, Paul Jerabek, Benjamin Klusemann, Zhaoping Lu, Thomas Klassen, Claudio Pistidda   +8 more
doaj   +1 more source

Thermodynamic Modeling of Complex Solid Solutions in the Lu-H-N System via Graph Neural Network Accelerated Monte Carlo Simulations

PRX Energy
Metal hydrides are important across diverse applications, such as hydrogen storage, batteries, gas sensors, nuclear reactions, and high-temperature superconductivity. Previous computational studies of metal hydrides under extreme pressures, e.g., O(10^{2}
Pin-Wen Guan, Catalin D. Spataru, Vitalie Stavila, Reese Jones, Peter A. Sharma, Matthew D. Witman   +5 more
doaj   +1 more source