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A pyrazolate-stabilized sodium hydride complex
Chemical Communications, 2015The synthesis and structural characterisation of the first sodium hydride complex stabilised by sterically demanding pyrazolate ligands are presented.
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Platinum hydride cluster complexes
Inorganic Chemistry, 1993The cluster cation [Pt[sub 3]([mu][sub 3]-H)([mu]-dppm)[sub 3]][sup +] (1) is easily and reversibly protonated to give [Pt[sub 3]([mu][sub 3]-H)[sub 2]([mu]-dppm)[sub 3]][sup 2][sup +] (3) or, in the presence of trifluoroacetate, [Pt[sub 3]H([mu][sub 3]-H)([mu]-O[sub 2]CCF[sub 3])([mu]-dppm)[sub 3]][sup +] (4).
Ravindranath Ramachandran +1 more
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Paramagnetic Transition Metal Hydride Complexes
Chemical ReviewsThe structures, bonding, energetics, preparation, characterization, and reactions, both stoichiometric and catalytic, are categorized for all paramagnetic hydride complexes (PHC) with terminal hydrides and then bridging hydrides: 58 and 177 crystallographically characterized, respectively, including 49 mixed-valence complexes.
Adi Fishkin, Robert H. Morris
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Reduction with complex metal hydrides
Journal of Chemical Education, 1957Focusses on the use of lithium aluminum hydride, aluminum hydride, magnesium aluminum hydride, sodium aluminum hydride, sodium borohydride, potassium borohydride, lithium borohydride, and lithium gallium hydride as analytical reducing reagents.
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Hydride Complexes of the Transition Metals
1965Publisher Summary This chapter discusses those discrete complexes of hydride that contain one or more hydrogen atoms bonded directly to a transition metal by an essentially covalent, two-electron bond. It is convenient and to some extent chemically significant to classify hydrides according to the nature of the other ligands attached to the metal ...
M.L.H. Green, D.J. Jones
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Complex Transition Metal Hydrides
Angewandte Chemie International Edition in English, 1988AbstractCompounds having structural units formed by transition metals and hydrogen have only become known fairly recently. Only the synthesis and structural characterization of ternary metal hydrides AxMyHz in which A is an alkali or alkaline‐earth metal and M is a transition metal, led to the discovery of anionic complex groups of the form [MHz ...
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Ionic conductivity in complex hydrides for energy storage applications: A comprehensive review
Chemical Engineering Journal, 2023Thi Thu Le +2 more
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