Probing Hydrogen Activation in a Dimetal Dihydride Complex by Symmetric Exchange with Parahydrogen. [PDF]
Matz JF +8 more
europepmc +1 more source
Divergent Synthesis of Polycyclic Derivatives via Gold Catalysis
Gold(I)‐catalyzed cycloisomerization enables the formation of complex 3D structures from simple enyne precursors. This study presents a divergent strategy to synthesize functionalized bicyclic and tricyclic scaffolds from a common alkynyl ketone.
Emilie Gentilini +4 more
wiley +1 more source
Tailoring hydrogenation, thermodynamic properties and oxidation resistance of TiFe alloy by only regulating the stoichiometric ratio of Ti and Fe elements. [PDF]
Xia S +8 more
europepmc +1 more source
Gold(I)‐Mediated Reactivity of Allenes With Mesoionic Nucleophiles: A Computational Exploration
The regioselective gold(I)‐mediated reactivity of allenes with mesoionic nucleophiles has been evaluated through computational analysis of the mechanisms involved. Instead of typical (3 + 2) pathways, sydnones and münchnones favour the formal (3 + 3) cyclizations affording substituted dihydropyridines.
Eduardo Garcia‐Padilla, Feliu Maseras
wiley +1 more source
The path to room-temperature superconductivity: A programmatic approach. [PDF]
Prasankumar RP +15 more
europepmc +1 more source
A new series of structurally rich polyaromatic isonitriles is presented as photoredox catalysts. Their photophysical properties are investigated by UV–Vis absorption and fluorescence measurements, combined with experimental and theoretical studies to evaluate both ground‐ and excited‐state redox properties.
Cristina Martini +9 more
wiley +1 more source
Flash Communication: Well-Defined Paramagnetic Polyhydrido-Bridged Iron-Iridium Clusters. [PDF]
Dubrawski Z +5 more
europepmc +1 more source
Bridging the gap. Beyond deck functionalization, the ethylene bridges of [2.2]paracyclophanes offer a largely unexploited reactivity landscape. This review showcases strategies to functionalize these bridges and leverage them to build novel cyclophane architectures.
Rongyu Sun +3 more
wiley +1 more source
Influence of Hydrogen-Incorporation on the Bulk Electronic Structure and Chemical Bonding in Palladium. [PDF]
Bannenberg LJ +8 more
europepmc +1 more source
Decomposition Dynamics of a New Noble-Gas Compound. [PDF]
Cohen A, Gerber RB.
europepmc +1 more source

