Results 261 to 270 of about 31,033 (331)

Probing Hydrogen Activation in a Dimetal Dihydride Complex by Symmetric Exchange with Parahydrogen. [PDF]

open access: yesJ Am Chem Soc
Matz JF   +8 more
europepmc   +1 more source

Divergent Synthesis of Polycyclic Derivatives via Gold Catalysis

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Gold(I)‐catalyzed cycloisomerization enables the formation of complex 3D structures from simple enyne precursors. This study presents a divergent strategy to synthesize functionalized bicyclic and tricyclic scaffolds from a common alkynyl ketone.
Emilie Gentilini   +4 more
wiley   +1 more source

Gold(I)‐Mediated Reactivity of Allenes With Mesoionic Nucleophiles: A Computational Exploration

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
The regioselective gold(I)‐mediated reactivity of allenes with mesoionic nucleophiles has been evaluated through computational analysis of the mechanisms involved. Instead of typical (3 + 2) pathways, sydnones and münchnones favour the formal (3 + 3) cyclizations affording substituted dihydropyridines.
Eduardo Garcia‐Padilla, Feliu Maseras
wiley   +1 more source

The path to room-temperature superconductivity: A programmatic approach. [PDF]

open access: yesProc Natl Acad Sci U S A
Prasankumar RP   +15 more
europepmc   +1 more source

Design, Synthesis, and Photophysical Studies of Functionalized Polyaromatic Isonitriles as Visible Light Photoredox Catalysts

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
A new series of structurally rich polyaromatic isonitriles is presented as photoredox catalysts. Their photophysical properties are investigated by UV–Vis absorption and fluorescence measurements, combined with experimental and theoretical studies to evaluate both ground‐ and excited‐state redox properties.
Cristina Martini   +9 more
wiley   +1 more source

Flash Communication: Well-Defined Paramagnetic Polyhydrido-Bridged Iron-Iridium Clusters. [PDF]

open access: yesOrganometallics
Dubrawski Z   +5 more
europepmc   +1 more source

Unlocking the Functionalization and Reactivity of Ethylene Bridges in [2.2]Paracyclophanes: Strategies and Challenges

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Bridging the gap. Beyond deck functionalization, the ethylene bridges of [2.2]paracyclophanes offer a largely unexploited reactivity landscape. This review showcases strategies to functionalize these bridges and leverage them to build novel cyclophane architectures.
Rongyu Sun   +3 more
wiley   +1 more source

Influence of Hydrogen-Incorporation on the Bulk Electronic Structure and Chemical Bonding in Palladium. [PDF]

open access: yesAdv Sci (Weinh)
Bannenberg LJ   +8 more
europepmc   +1 more source

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