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THE RELATIONSHIP BETWEEN THE CHEMICAL STRUCTURE OF IА–VIIА SUBGROUPS METAL HYDRIDES (NON-METALS) OF D.I. MENDELEEV’S PERIODIC TABLE AND THEIR FIRE AND EXPLOSIVE PROPERTIES [PDF]

open access: yesАктуальные вопросы пожарной безопасности
An analysis of the relationship between the chemical structure of IA–VIIA subgroups metal hydrides (nonmetals) of D.I. Mendeleev’s periodic table and their fire and explosive properties has been performed.
Leonid P. Vogman, Alexandr V. Ilyichev
doaj   +1 more source

Techno-Economic Analysis of Hydrogen Storage Technologies for Railway Engineering: A Review

open access: yesEnergies, 2022
According to the specific requirements of railway engineering, a techno-economic comparison for onboard hydrogen storage technologies is conducted to discuss their feasibility and potentials for hydrogen-powered hybrid trains.
Zhan Xu   +4 more
doaj   +1 more source

Effects of carbon on hydrogen storage performances of hydrides [PDF]

open access: yes, 2010
The development of hydrogen storage materials with high performance has been attracting considerable attention in recent years. Magnesium hydride, alanates, borohydrides and ammonia borane are the most promising candidates due to their high hydrogen ...
Wu, Chengzhang   +2 more
core   +1 more source

Complex and liquid hydrides for energy storage [PDF]

open access: yes, 2016
The research on complex hydrides for hydrogen storage was initiated by the discovery of Ti as a hydrogen sorption catalyst in NaAlH4 by Boris Bogdanovic in 1996.
Hauback, Bjorn C.   +58 more
core   +1 more source

Direct synthesis of pure complex aluminium hydrides by cryomilling [PDF]

open access: yes, 2010
Simple mechanochemical procedures can be used for the solid-state preparation of stable complex aluminium hydrides as hydrogen storage materials. For the synthesis of unstable complex hydrides, cryomilling at temperatures at which product decomposition ...
Pommerin, A.   +3 more
core   +1 more source

Complex Hydrides – When Powder Diffraction needs Help

open access: yesCHIMIA, 2014
'Real life' energy-related materials such as solid-state hydrogen storage compounds or components of electrochemical cells are usually polycrystalline, poorly crystallized, highly reactive and dynamic systems.
Pascal Schouwink, Radovan Černý
doaj   +1 more source

Accessing the main-group metal formyl scaffold through CO-activation in beryllium hydride complexes

open access: yesNature Communications, 2022
Stoichiometric carbon monoxide insertion processes leading to metal-formyl complexes are scarce, even for transition metals. Here, light is shed on the underexplored chemistry of beryllium hydrides leading to a stable example of a main group metal-formyl
Terrance J. Hadlington, Tibor Szilvási
doaj   +1 more source

Combined Effect of Halogenation and SiO2 Addition on the Li-Ion Conductivity of LiBH4

open access: yesInorganics, 2023
In this work, the combined effects of anion substitution (with Br− and I−) and SiO2 addition on the Li-ion conductivity in LiBH4 have been investigated. Hexagonal solid solutions with different compositions, h-Li(BH4)1−α(X)α (X = Br, I), were prepared by
Valerio Gulino   +4 more
doaj   +1 more source

Alkyl and hydride-olefin complexes of niobocene [PDF]

open access: yesJournal of Organometallic Chemistry, 1980
Reactions of Cp2NbCl2 with RMgCl (R = n-C3H7, i-C3H7, n-C4H9, s-C4H9 and n-C5H11) give niobocene hydride olefin complexes Cp2Nb(H)L (L = C3H6, C4H8 and C5H10). The last step of the reaction probably proceeds via a stereospecific β-H elimination from the monoalkyl species Cp2NbR.
Klazinga, A.H., Teuben, J.H.
openaire   +2 more sources

Complex Hydrides for Hydrogen Storage [PDF]

open access: yes, 2003
This report describes research into the use of complex hydrides for hydrogen storage. The synthesis of a number of alanates, (AIH4) compounds, was investigated.
Michael D. Hampton   +3 more
core   +1 more source

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