Results 51 to 60 of about 10,236 (282)

Phase Engineering of Atomically Precise Nanoclusters (APNCs) of Gold and Beyond

open access: yesAdvanced Materials, EarlyView.
Engineering the structural phase of materials is of paramount importance for both fundamental research and practical applications. In this Review, we summarize the recent progress in controlling the phases of atomically precise nanoclusters (APNCs) of gold, silver and copper, as well as bimetallic systems. The phase‐enabled material properties of APNCs
Yitong Wang   +4 more
wiley   +1 more source

Rotation of complex ions with ninefold hydrogen coordination studied by quasielastic neutron scattering and first-principles molecular dynamics calculations

open access: yesPhysical Review Research, 2022
Quasielastic neutron scattering (QENS) and neutron powder diffraction of the complex transition metal hydrides Li_{5}MoH_{11} and Li_{6}NbH_{11} were measured in a temperature range of 10–300 K to study their structures and dynamics, especially the ...
Yoshinori Ohmasa   +12 more
doaj   +1 more source

Development and Characterization of Novel Complex Hydrides Synthesized via Molten State Processing [PDF]

open access: yes, 2005
This study is aimed at developing novel hydrides for hydrogen storage through a new synthesis technique utilizing high hydrogen overpressure at elevated temperatures denoted as Molten State Processing, MSP. This synthesis technique holds the potential of
Donald L. Anton   +4 more
core   +1 more source

Ultrathin Li Metal Anodes: Quantitative Design Principles and Manufacturability Across Liquid and Solid‐State Batteries

open access: yesAdvanced Materials, EarlyView.
Ultrathin lithium metal anodes (≤15 µm) offer a promising route to high‐energy‐density batteries due to their high capacity and low potential. This review presents design principles for ultrathin Li, evaluates fabrication strategies, and discusses challenges in liquid and solid‐state cells.
Cheng Wang   +9 more
wiley   +1 more source

Investigation of Catalytic Effects and Compositional Variations in Desorption Characteristics of LiNH2-nanoMgH2

open access: yesApplied Sciences, 2017
LiNH2 and a pre-processed nanoMgH2 with 1:1 and 2:1 molar ratios were mechano-chemically milled in a high-energy planetary ball mill under inert atmosphere, and at room temperature and atmospheric pressure.
Sesha S. Srinivasan   +3 more
doaj   +1 more source

Thermal destabilization of binary and complex metal hydrides by chemical reaction: A thermodynamic analysis [PDF]

open access: yes, 2006
Some alkali and alkali-earth metal hydrides and their complex hydrides have very high hydrogen storage capacities and reversibility. Unfortunately, most of them have decomposition temperatures that are too high.
Shim, JH, Cho, YW, Lee, BJ
core   +1 more source

Design of High‐Energy Anode for All‐Solid‐State Lithium Batteries–A Model with Borohydride‐Based Electrolytes

open access: yesAdvanced Materials Interfaces, EarlyView.
This study proposes a function‐sharing anode design to enable nonmetallic lithium insertion while maintaining intimate interfacial contact with the solid‐state electrolyte. A combination of lithium‐compatible and conformable borohydrides, highly conformable indium metal, less‐graphitized acetylene black, and a layer of highly graphitized massive ...
Keita Kurigami   +3 more
wiley   +1 more source

Complex hydrides for CO2 reduction [PDF]

open access: yes
Fossil fuels consumption is not expected to decrease significantly in the next decade, driving the atmospheric carbon dioxide concentration upward. Tremendous efforts have been made in the field of carbon capture with the development of porous material ...
Lombardo, Loris   +3 more
core   +1 more source

Complex transition metal hydrides: Linear correlation of countercation electronegativity versus T-D bond lengths [PDF]

open access: yes, 2015
© 2015 The Royal Society of Chemistry. For homoleptic 18-electron complex hydrides, an inverse linear correlation has been established between the T-deuterium bond length (T = Fe, Co, Ni) and the average electronegativity of the metal countercations ...
Buckley, Craig   +2 more
core   +1 more source

Combined {DFT} and geometrical{ extendash}topological analysis of Li-ion conductivity in complex hydrides [PDF]

open access: yes, 2020
On the basis of DFT calculations, Li-ion migration was analyzed for LiBH4, LiNH2, Li2NH, Li2BH4NH2, Li4BH4(NH2)(3)and Li-5(BH4)(3)NH complex hydrides by means of the nudged elastic band method.
Davide M. Proserpio   +13 more
core   +1 more source

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