Results 121 to 130 of about 23,448 (288)

Selective Oxidation Strategies for Cost‐Efficient Green Hydrogen Production via Hybrid Water Electrolysis

open access: yesCarbon Energy, EarlyView.
Hybrid water electrolysis has emerged as a promising alternative to conventional electrolysis for sustainable hydrogen production. The economic potential of replacing water oxidation with organic substrates is assessed. For each substrate, representative electrocatalysts and mechanistic insights are reviewed to identify design principles for optimized ...
Conor Brennan‐Pollak   +12 more
wiley   +1 more source

Hydride formation pressures and kinetics in individual Pd nanoparticles with systematically varied levels of plastic deformation

open access: yesNature Communications
Pd nanoparticles, together with bulk and thin film Pd, constitute the archetype model system for metal-hydrogen interactions. The density of defects in Pd nanoparticles, such as grain boundaries and dislocations, combined with their size, shape ...
Carl Andersson   +4 more
doaj   +1 more source

In Situ Grown Bimetallic (Ni, Fe)12P5 Nanoneedles With Favorable Electronic Structures and Superwetting Surfaces for Highly Efficient and Durable Seawater Splitting at Industrial Current Density

open access: yesCarbon Energy, EarlyView.
A three‐dimensional bimetallic (Ni, Fe)12P5 nanoneedle array anchored on metal foam with superwetting surfaces and modulated electronic structures is in situ fabricated via a facile one‐step phosphidation strategy (Fe–Ni12P5 NAs@NFF). This material demonstrates exceptional bifunctional activity and long‐term stability at the industrial‐scale current ...
Jingcheng Zhang   +7 more
wiley   +1 more source

Photothermal CO2 Hydrogenation: Reactions, Mechanisms, and Catalyst Design

open access: yesCarbon Energy, EarlyView.
Reactions, mechanisms, and catalyst design for photothermal CO2 hydrogenation. ABSTRACT Photothermal CO2 hydrogenation has attracted extensive attention because it provides a green and sustainable approach to fuel and chemicals production. The photothermal catalyst plays a critical role in CO2 conversion through a range of reactions.
Shuai Yan   +15 more
wiley   +1 more source

Reduction with Complex Metal Hydrides. [PDF]

open access: yesJournal of the American Chemical Society, 1956
openaire   +2 more sources

An Ambient Photocatalytic Approach to In‐Situ Prepare Cobalt/Cobalt Phosphide and Cobalt/Cobalt Phosphide@Graphene Heterojunction Nanomaterials With Optimized Charge Separation Effects for Highly Efficient Relayed Electrocatalytic NOX− Reduction to NH3

open access: yesCarbon Energy, EarlyView.
A visible‐light‐driven ambient photocatalytic method in‐situ fabricates Co/CoP‐x and Co/CoP@rGO heterojunction with enhanced charge separation, enabling highly efficient relayed electrocatalytic NOx− reduction to NH3 with outstanding Faraday efficiency and ammonia productivity.
Xin Zhao   +7 more
wiley   +1 more source

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

open access: yesChemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

Methyl on the Bridge: 2‐Methyl Propellane as Precursor for 1,3‐Substituted 2‐Methylated Bicyclo[1.1.1]Pentanes

open access: yesChemistry – A European Journal, EarlyView.
The synthesis of 2‐methyl propellane and its conversion to various 1,2‐ and 1,2,3‐di‐ and trisubstituted bicyclopentanes is reported. Abstract Bicyclo[1.1.1]pentanes (BCPs) have emerged as isosteric replacements for mono‐ and para‐substituted benzene rings in medicinal and materials applications, involving substitution at the BCP bridgehead (1,3 ...
Sean R. Verschaeve   +4 more
wiley   +1 more source

Protonation‐Induced Electron Density Redistribution Facilitates Aggregation in PNNP Dicopper Hydride Complexes

open access: yesChemistry – A European Journal, EarlyView.
Copper(I) hydride complexes often exhibit diverse aggregation behavior that can profoundly influence their structure and reactivity. In this study we use a combined experimental and computational approach to identify key structural an electronic factors that govern aggregation in PNNP dicopperhydride complexes.
Roel Laurentius Maria Bienenmann   +5 more
wiley   +1 more source

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