Results 141 to 150 of about 436,832 (272)
This is a comprehensive study of new family of high functionalized meso‐tetraarylporphyrins. A synthetic approach to phosphonate‐substituted fluorinated porphyrins was developed. These compounds were investigated with respect to singlet oxygen generation and photostability.
Azhar Kechiche +8 more
wiley +1 more source
Computational analysis of X<sub>2</sub>CaZnH<sub>6</sub> (X = K, Rb and Cs) hydrides for hydrogen storage. [PDF]
Al-Zoubi N +4 more
europepmc +1 more source
A fully noble‐metal‐free photocatalytic system that couples cobaloxime catalysis with Cu photosensitizer for HAT‐driven acetylene‐to‐ethylene conversion is reported. ABSTRACT The purification of ethylene streams from acetylene impurities remains a key industrial challenge, for which light‐powered strategies are emerging as sustainable alternatives to ...
Anna Fortunato +5 more
wiley +1 more source
Hydrogen Occupancy, Site Hierarchy, and Hydride-Transformation Pathways in BCC High-Entropy Alloys. [PDF]
Chen C, Hou Q, Gao L, Ding Z.
europepmc +1 more source
Homo‐ and heterodinuclear group 4 metallocene complexes of the type [(Cp2M)2(μ‐Me)(μ‐C2R)] (M = Ti, Zr) are active catalysts for the polymerization of ethylene in the presence of aluminium‐free activators. The catalytically active species are proposed to have dinuclear character and depending on the type of activator, unique reactivity was observed ...
Hanan Al Hamwi +8 more
wiley +1 more source
Electronic Effects Drive Selectivity in CO<sub>2</sub> Reduction Catalysis by Heptacoordinated Cobalt Complexes. [PDF]
Droghetti F +5 more
europepmc +1 more source
Flipping the Card With Enantiodivergent Organocatalysis
This minireview elaborates on recent organocatalytic strategies for achieving enantiodivergence—the ability to access both product enantiomers using a single chiral catalyst. It highlights how achiral stimuli, such as solvent polarity and chemical additives, along with minimal catalyst modifications, trigger stereochemical inversions in reactions ...
Debora Iapadre +3 more
wiley +1 more source
Physically interpretable descriptors drive the materials design of metal hydrides for hydrogen storage. [PDF]
Jang SH +7 more
europepmc +1 more source
Episulfones. III. Reductive Cleavage of Episulfones by Complex Metal Hydrides
Shoichi Matsumura, T. Nagai, N. Tokura
semanticscholar +1 more source
The Role of Iron‐Hyponitrite Intermediates in Biology and Insights From Synthetic Model Complexes
Despite the difference in active site architecture, NO reduction by different NOR enzymes is expected to be linked by a common intermediate: hyponitrite (N2O22−). However, experimentally, very little is known about the coordination chemistry of iron with hyponitrite and the expected Fe‐hyponitrite intermediates.
Michael O. Lengel, Nicolai Lehnert
wiley +1 more source

