State‐of‐the‐Art and Synthetic Challenges for Hydrosilane Production
Chemistry – A European Journal, EarlyView.The synthesis of hydrosilanes is currently energy intensive and their recycling is not considered. However, these compounds are important in many industrial fields but also for the valorization of oxygenated waste, towards a circular economy. This review compares the available synthetic routes and highlights the remaining challenges for the production ...
Gabriel Durin +3 more
wiley +1 more source
An Electron‐Poor Nickel Diphosphine Complex: Synthesis, Structure, and Reactivity of Ni(dFppe)2
Chemistry – A European Journal, EarlyView.Fluorinated diphosphine ligands such as 1,2‐bis[bis(pentafluorophenyl)phosphino]ethane (dFppe) offer powerful electronic tunability and unusual reactivity. Despite known analogues of the heavier congeners Pd and Pt, Ni complexes of dFppe remain conspicuously absent.
A. Dina Dilinaer, Marcus W. Drover
wiley +1 more source
Synthesis of high-entropy hydride from the cantor alloy (fcc-CoCrFeNiMn) at extreme conditions. [PDF]
Nat CommunGlazyrin K +18 more
europepmc +1 more source
Cationic Sulfonium‐Based Tripodal Ligand and Its Rh(I) Complexes
Chemistry – A European Journal, EarlyView.We report a cationic EP3‐type tripodal ligand based on an aromatic sulfonium cation (E = S+) along with a series of its Rh(I) complexes. Structural, spectroscopic, electrochemical, and computational analyses of these complexes compared to isostructural analogs (E = Si− or P) reveal pronounced electron density depletion at Rh in the sulfonium congener ...
Nitsan Barel +5 more
wiley +1 more source
From Unlocking Pyruvate Hyperpolarization by Signal Amplification by Reversible Exchange (SABRE) to Clinical Prospects. [PDF]
ACS OmegaIali W.
europepmc +1 more source
Metal complexes of weakly coordinating anions. Precursors of strong cationic organometallic Lewis acids [PDF]
, 1988 Beck, Wolfgang, Sünkel, Karlheinz
core +1 more source
Alkali‐Metal Base Catalyzed Electrocyclization of Isoprene Derivatives
Chemistry – A European Journal, EarlyView.Simple and abundant alkali‐metal base catalysis in combination with Lewis basic polyamines enables the electrocyclization of isoprene‐derived trienes to cycloheptadienes under neat conditions. Mechanistic insight supported by DFT guides a scalable route to seven‐membered carbocycles which, after reduction, give saturated cycloalkanes relevant as ...
Mikaël Le Roch +3 more
wiley +1 more source
Stability and hydrogen storage performance of Na<sub>2</sub>LiXH<sub>6</sub> (X = Zr, V, Cr) double perovskite hydrides <i>via</i> DFT and AIMD. [PDF]
RSC AdvKaleem M, Asif Iqbal MM, Khan AN.
europepmc +1 more source
The Reduction of 2'-Hydroxychalcone by Complex Metal Hydrides. [PDF]
Acta Chemica Scandinavica, 1968 Tapio Hase, Sven Liisberg, Jerker Porath
openaire +1 more source