Results 171 to 180 of about 436,832 (272)

Identification of Au-hydrides as key intermediates in the reduction of Au(iii) prodrugs to active Au(i) species under protic conditions. [PDF]

Chem Sci
Ochs J, Metzler-Nolte N.
europepmc   +1 more source

Main Group Metals in Redox Catalysis

European Journal of Inorganic Chemistry, EarlyView.
Main group metal redox catalysis is emerging as a credible alternative to transition metal chemistry. Elements from groups 13 to 15 now enable diverse catalytic manifolds, driven by ligand design and control of electronic structure. This review highlights recent advances, key design principles, and remaining challenges, positioning main group metals as
Olympia Mouriki, Alba Martinez‐Bascuñana, Oriol Planas   +2 more
wiley   +1 more source

Cu₁₄H₁₂(P<i>^t</i>Bu₃)₆Cl₂-The Expanse of Stryker's Reagent. [PDF]

Molecules
Strienz M, Kimmich R, Conzelmann A, Schnepf A.   +3 more
europepmc   +1 more source

Design, Synthesis, and Photophysical Studies of Functionalized Polyaromatic Isonitriles as Visible Light Photoredox Catalysts

European Journal of Organic Chemistry, EarlyView.
A new series of structurally rich polyaromatic isonitriles is presented as photoredox catalysts. Their photophysical properties are investigated by UV–Vis absorption and fluorescence measurements, combined with experimental and theoretical studies to evaluate both ground‐ and excited‐state redox properties.
Cristina Martini, Camilla Russo, Jussara Amato, Carmine Volpe, Francesca Brunelli, Laurence Grimaud, Maxime R. Vitale, Greta Donati, Andrea Basso, Mariateresa Giustiniano   +9 more
wiley   +1 more source

Structural and reactivity investigations using organo-copper(i) and zinc(ii) complexes with hydrogen and carbon dioxide. [PDF]

Chem Sci
Cowie BE, Phanopoulos A, Shaffer MSP, Williams CK.   +3 more
europepmc   +1 more source

Mechanistic and Reactivity Insights into Diboron‐Mediated NN and NN Bond Scission

European Journal of Organic Chemistry, EarlyView.
This review highlights the emerging ability of diboron reagents to cleave both π‐bonded (N=N) and σ‐bonded (N—N) nitrogen–nitrogen linkages, integrating mechanistic understanding with recent synthetic applications. Diboron reagents have emerged as versatile reducing agents capable of transforming a broad range of functional groups through pathways like
Raúl Valderrama‐Callejón, Inés Alonso, M. Belén Cid   +2 more
wiley   +1 more source

Influence of Hydrogen-Incorporation on the Bulk Electronic Structure and Chemical Bonding in Palladium. [PDF]

Adv Sci (Weinh)
Bannenberg LJ, García-Martínez F, Lömker P, Engel RY, Schlueter C, Schreuders H, Navarathna A, Ratcliff LE, Regoutz A.   +8 more
europepmc   +1 more source

Iminodirhodium‐ and Iminocopper‐Catalyzed CH Activation: Chemoselective Oxidation of Alcohols and Aldehydes via Intermolecular Hydride Abstraction

European Journal of Organic Chemistry, EarlyView.
Chemoselective hydride abstractor iminometalloids, derived from O‐mesylacetoxime (MAO) using Rh2(II/II) or Cu(I) catalysts, can activate the C–Hα bonds of alcohols and aldehydes ultimately forming ketones, carboxylic acids, and esters even in the presence of C–H bonds with comparable bond strengths.
Raghunath Reddy Anugu, John R. Falck, Adeniyi M. Adebesin   +2 more
wiley   +1 more source

Influence of B'-site vacancy on hydrogen storage, structural, elastic, thermodynamic and optoelectronic attributes of potassium based double perovskite K₂LiAlH₆hydride for green energy applications. [PDF]

Sci Rep
Murtaza H, Habib MA, Ain Q, Kumar A, Munir J, Ibrahim ABM, Oza AD, Al-Salimi MSS.   +7 more
europepmc   +1 more source