1,1‐Disubstituted vinylbromides are key intermediates for constructing nitrogen‐containing heterocycles. This review provides an overview of the synthetic applications of 1,1‐disubstituted vinylbromides and summarizes recent developments in reaction methodologies, mechanistic insights, and the structural diversity of N‐heterocyclic compounds accessible
Anne Westermeyer +6 more
wiley +1 more source
Influence of B'-site vacancy on hydrogen storage, structural, elastic, thermodynamic and optoelectronic attributes of potassium based double perovskite K<sub>2</sub>LiAlH<sub>6</sub>hydride for green energy applications. [PDF]
Murtaza H +7 more
europepmc +1 more source
Emerging Trends in Organic Photoreactions Utilizing Disulfides
Disulfides are versatile, nontoxic alternatives to metal photocatalysts. This review explores their role as photoactivated thiyl‐radical precursors and bifunctional catalysts (HAT/electron shuttling) in diverse transformations. Strategies for electronic tuning and development into recyclable heterogeneous materials are highlighted for sustainable ...
Sunil Kumar +3 more
wiley +1 more source
Deep learning generative model for conditional crystal structure prediction of sodium amide. [PDF]
Guan R, Liu A, Song Y.
europepmc +1 more source
1,2‐Diazetidines − Structure, Synthesis, and Functionalization
1,2‐Diazetidines are saturated four‐membered heterocycles featuring two adjacent nitrogen atoms. Despite recent advances in their synthesis and promising potential in medicinal chemistry, the chemistry of these cyclic hydrazines remains underexplored.
Stefan Roesner
wiley +1 more source
Solvent-temperature coupled hydride transfer controls product selectivity in the HSiR<sub>3</sub>/KO <sup><i>t</i></sup> Bu catalytic system. [PDF]
Yao H, Zhou Z, Liu Y, Zhang DH, Li G.
europepmc +1 more source
Divergent Synthesis of Polycyclic Derivatives via Gold Catalysis
Gold(I)‐catalyzed cycloisomerization enables the formation of complex 3D structures from simple enyne precursors. This study presents a divergent strategy to synthesize functionalized bicyclic and tricyclic scaffolds from a common alkynyl ketone.
Emilie Gentilini +4 more
wiley +1 more source
Thermal Management in Metal Hydride Hydrogen Storage Reactors: Mechanisms, Architectures, and Design Trade-Offs. [PDF]
Hou Q +8 more
europepmc +1 more source
Gold(I)‐Mediated Reactivity of Allenes With Mesoionic Nucleophiles: A Computational Exploration
The regioselective gold(I)‐mediated reactivity of allenes with mesoionic nucleophiles has been evaluated through computational analysis of the mechanisms involved. Instead of typical (3 + 2) pathways, sydnones and münchnones favour the formal (3 + 3) cyclizations affording substituted dihydropyridines.
Eduardo Garcia‐Padilla, Feliu Maseras
wiley +1 more source
Probing Hydrogen Activation in a Dimetal Dihydride Complex by Symmetric Exchange with Parahydrogen. [PDF]
Matz JF +8 more
europepmc +1 more source

