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Direct Synthesis of Complex Metal Hydrides
Inorganic Chemistry, 1963The direct synthesis of NaAlH/sub 4/, LiAlH/sub 4/, KAlH/sub 4/, and CsAlH/sub 4/ from the elements was accomplished. The reaction of the alkali metal, aluminum, and hydrogen proceeds at moderate temperatures and pressures to produce nearly quantitative yields of high purity alkali metal aluminum hydride.
E. C. Ashby, G. J. Brendel, H. E. Redman
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The Reduction of Nitrogen Heterocycles with Complex Metal Hydrides
1966Publisher Summary The reactions of complex metal hydrides occur by an attack of the nucleophilic hydride ion on an electrophilic center. Aromatic nitrogen heterocycles in which the nitrogen contributes only one electron to the π-system are electrophilic as compared to benzene, and show a reduction by lithium aluminum hydride, an active reducing agent.
Robert E. Lyle, Paul S. Anderson
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Complex light metal hydrides are promising candidates for efficient, compact solid-state hydrogen storage. (De)hydrogenation of these materials often proceeds via multiple reaction intermediates, the energetics of which determine reversibility and ...
Shinyoung Kang +2 more
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Crystal structure evolution of complex metal aluminum hydrides upon hydrogen release
Journal of Energy Chemistry, 2020Complex aluminum hydrides have been widely studied as potential hydrogen storage materials but also, for some time now, for electrochemical applications.
Claudia Weidenthaler
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Ammonia–Borane and Amine–Borane Dehydrogenation Mediated by Complex Metal Hydrides
Chemical Reviews, 2016Andrea Rossin, Maurizio Peruzzini
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Recent advances in the 18-electron complex transition metal hydrides of Ni, Fe, Co and Ru
Terry D Humphries +2 more
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Thermal decomposition of complex metal hydrides
Inorganic Chemistry, 1972J. A. Dilts, E. C. Ashby
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