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Direct Synthesis of Complex Metal Hydrides

Inorganic Chemistry, 1963
The direct synthesis of NaAlH/sub 4/, LiAlH/sub 4/, KAlH/sub 4/, and CsAlH/sub 4/ from the elements was accomplished. The reaction of the alkali metal, aluminum, and hydrogen proceeds at moderate temperatures and pressures to produce nearly quantitative yields of high purity alkali metal aluminum hydride.
E. C. Ashby, G. J. Brendel, H. E. Redman
openaire   +2 more sources

The Reduction of Nitrogen Heterocycles with Complex Metal Hydrides

1966
Publisher Summary The reactions of complex metal hydrides occur by an attack of the nucleophilic hydride ion on an electrophilic center. Aromatic nitrogen heterocycles in which the nitrogen contributes only one electron to the π-system are electrophilic as compared to benzene, and show a reduction by lithium aluminum hydride, an active reducing agent.
Robert E. Lyle, Paul S. Anderson
openaire   +2 more sources

Morphology‐Dependent Stability of Complex Metal Hydrides and Their Intermediates Using First‐Principles Calculations

open access: yesChemPhysChem, 2019
Complex light metal hydrides are promising candidates for efficient, compact solid-state hydrogen storage. (De)hydrogenation of these materials often proceeds via multiple reaction intermediates, the energetics of which determine reversibility and ...
Shinyoung Kang   +2 more
exaly   +2 more sources

Crystal structure evolution of complex metal aluminum hydrides upon hydrogen release

Journal of Energy Chemistry, 2020
Complex aluminum hydrides have been widely studied as potential hydrogen storage materials but also, for some time now, for electrochemical applications.
Claudia Weidenthaler
exaly   +2 more sources

Recent advances in the 18-electron complex transition metal hydrides of Ni, Fe, Co and Ru

open access: yesCoordination Chemistry Reviews, 2017
Terry D Humphries   +2 more
exaly   +2 more sources

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