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The stereochemistry of reduction by complex metal hydrides
Experientia, 1960Die gegenwartig akzeptierte Theorie des Mechanismus der Reduktion von Ketonen mit Metallhydriden wird diskutiert. Verschiedene Unstimmigkeiten werden aufgezeigt, und ein neuer Mechanismus wird vorgeschlagen, der mit den experimentellen Befunden besser ubereinstimmt.
D. M. S. Wheeler, J. W. Huffman
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Complex Transition Metal Hydrides
Angewandte Chemie International Edition in English, 1988AbstractCompounds having structural units formed by transition metals and hydrogen have only become known fairly recently. Only the synthesis and structural characterization of ternary metal hydrides AxMyHz in which A is an alkali or alkaline‐earth metal and M is a transition metal, led to the discovery of anionic complex groups of the form [MHz ...
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A tetraphenylcyclobutadiene complex of a metal carbonyl hydride
Journal of the Chemical Society D: Chemical Communications, 1970The tetraphenylcyclobutadiene derivative C5H5Mo(CO)C4Ph4Cl reacts with Me3CMgCl in diethyl ether to give yellow crystalline relatively air-stable C5H5Mo(CO)C4Ph4H, the first example of a cyclobutadiene–metal complex with a metal–hydrogen bond.
R. B. King, A. Efraty
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Bimetallic Transition Metal Hydride Complexes
Russian Chemical Reviews, 1983The literature data on bimetallic transition metal hydride complexes containing metal–hydrogen bonds and non-transition metal atoms are described systematically and discussed. The principal methods of synthesis of these compounds and ways of stabilising them in the lowest oxidation state by cyclopentadienyl and other electron-donating ligands are ...
Grigorii L Soloveichik, Boris M Bulychev
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Hydride transfer reactions catalysed by metal complexes
Journal of the Chemical Society B: Physical Organic, 1966IN the course of an investigation of the catalytic action of certain metal complexes in hydride transfer reactions it was observed that rhodium chloride catalysed the dehydrogenation of isopropanol to acetone. During the reaction rhodium metal was precipitated, and it was found that the rate of dehydrogenation decreased as rhodium was removed from ...
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Hydrogen storage and evolution catalysed by metal hydride complexes
Dalton Trans., 2013The storage and evolution of hydrogen are catalysed by appropriate metal hydride complexes. Hydrogenation of carbon dioxide by hydrogen is catalysed by a [C,N] cyclometalated organoiridium complex, [Ir(III)(Cp*)(4-(1H-pyrazol-1-yl-κN(2))benzoic acid-κC(3))(OH(2))](2)SO(4) [Ir-OH(2)](2)SO(4), under atmospheric pressure of H(2) and CO(2) in weakly basic ...
Shunichi, Fukuzumi, Tomoyoshi, Suenobu
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Complex metal aluminium hydrides
The first complex metal hydride to be considered potentially interesting for practical hydrogen storage applications, owing to its relatively high hydrogen storage capacity and moderate thermodynamic stability was an alanate. Alanates (alumino-hydrides) are complex hydrides where a metallic cation coordinates an anion with Al in the center via an ionicWeidenthaler, C., Pistidda, C.
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New iron(II) complex metal hydrides with SrMg2FeH8 type structure
Journal of Alloys and Compounds, 1995Baoquan Huang, K. Yvon, P. Fischer
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Synthesis of Metal Complex Hydrides for Hydrogen Storage
The Journal of Physical Chemistry C, 2007A new procedure for the direct synthesis of metal complex hydrides, NaAlH4 and LiAlH4, has been developed through hydrogenation of their respective metal hydrides, NaH and LiH, with Al, both in the presence of a catalyst and in the presence of a liquid complexing agent.
Jun Wang +2 more
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