Results 181 to 190 of about 23,448 (288)

Search for thermodynamically stable ambient-pressure superconducting hydrides in the GNoME database. [PDF]

Commun Phys
Sanna A, Cerqueira TFT, Cubuk ED, Errea I, Fang YW.   +4 more
europepmc   +1 more source

Masked Silylenes: Controlled Generation and Reactivity Under Thermal and Equilibrium Conditions

European Journal of Inorganic Chemistry, EarlyView.
This Review provides an overview of masked silylenes as bench‐stable precursors that release silylenes (R2Si:) under thermal activation or reversible equilibria. Precursor preparation, generation pathways, and characteristic reactivity are summarized, including trapping chemistry, reversible interconversions, insertion‐type processes, and small ...
Kei Ota, Kanata Miyahara, Norio Nakata
wiley   +1 more source

Identification of Au-hydrides as key intermediates in the reduction of Au(iii) prodrugs to active Au(i) species under protic conditions. [PDF]

Chem Sci
Ochs J, Metzler-Nolte N.
europepmc   +1 more source

Ligand‐Level Chemical Activation: Coordination with Benefits

European Journal of Inorganic Chemistry, EarlyView.
While often perceived as a liability, ligand‐based reactivity in carefully designed settings becomes a powerful synthetic tool. The key to streamlined processes overriding classical ionic reactivity is the selective electron redistribution induced by metal coordination. This enables storage of electrons and protons or incorporation of functional groups
Oscar Charpentier, Agnideep Das, Marine Desage‐El Murr   +2 more
wiley   +1 more source

Cu₁₄H₁₂(P<i>^t</i>Bu₃)₆Cl₂-The Expanse of Stryker's Reagent. [PDF]

Molecules
Strienz M, Kimmich R, Conzelmann A, Schnepf A.   +3 more
europepmc   +1 more source

Artificial [FeFe]‐Hydrogenase Mimics From Ferrocenyl Thioketone‐Functionalized Triphenylamine and (Bi)thiophene Derivatives: Synthesis, Characterization, and Hydrogen Evolution Catalysis

European Journal of Inorganic Chemistry, EarlyView.
Synthesis of ferrocenyl thioketone‐functionalized triphenylamine and triphenylamine‐(bi)thiophene derivatives as proligands for the assembly of artificial [FeFe]‐hydrogenase active site models. Thiocarbonyl compounds, especially thioketones, have emerged as promising precursors for constructing [FeFe]‐hydrogenase mimics that can mediate hydrogen ...
Hassan Abul‐Futouh, Ibrahim Basma, Sara J. Abaalkhail, Ahmad Q. Daraosheh, Phil Köhler, Wolfgang Weigand   +5 more
wiley   +1 more source

Influence of Hydrogen-Incorporation on the Bulk Electronic Structure and Chemical Bonding in Palladium. [PDF]

Adv Sci (Weinh)
Bannenberg LJ, García-Martínez F, Lömker P, Engel RY, Schlueter C, Schreuders H, Navarathna A, Ratcliff LE, Regoutz A.   +8 more
europepmc   +1 more source

Push–Pull Ynamines and Push–Pull Ynamides: Synthesis, Structure, Reactivity, and Application

European Journal of Organic Chemistry, EarlyView.
Push–pull ynamines and push–pull ynamides, which carry an EWG and an amino or amido group as EDG, are highly interesting classes of EDG‐EWG alkynes that have been intensively studied due to their exceptional reactivity. In this review, the synthesis, structure, reactivity, and application of push–pull ynamines, push–pull ynecarbamates, push–pull ...
Hans‐Joachim Gais
wiley   +1 more source

Structural and reactivity investigations using organo-copper(i) and zinc(ii) complexes with hydrogen and carbon dioxide. [PDF]

Chem Sci
Cowie BE, Phanopoulos A, Shaffer MSP, Williams CK.   +3 more
europepmc   +1 more source