Results 51 to 60 of about 6,959 (207)

Hyperpolarization of Molecular Deuterium

Angewandte Chemie, EarlyView.
Hyperpolarized molecular deuterium is generated and detected using a nonhydrogenative SABRE catalyst with nicotinamide. The resonance shows a strongly enhanced partially negative line, substrate‐dependent and sensitive to transient intermediates.
Theresa L. K. Hune, Anakin Aden, Julius F. Matz, Denis Moll, Ilya Kuprov, Stefan Glöggler   +5 more
wiley   +2 more sources

Computational discovery of Li-based tetragonal LiFeH4 and LiCoH4 complex hydrides as efficient solid-state hydrogen storage materials for practical applications

Energy Conversion and Management: X
The development of efficient, safe, and high-capacity solid-state hydrogen storage materials remains a major challenge for the realization of a sustainable hydrogen-based energy economy.
Minhajul Islam
doaj   +1 more source

Crystal Structural Determination of SrAlD5 with Corner-Sharing AlD6 Octahedron Chains by X-ray and Neutron Diffraction

Crystals, 2018
Aluminium-based complex hydrides (alanates) composed of metal cation(s) and complex anion(s), [AlH4]− or [AlH6]3− with covalent Al–H bonds, have attracted tremendous attention as hydrogen storage materials since the discovery of the reversible hydrogen ...
Toyoto Sato, Shigeyuki Takagi, Magnus H. Sørby, Stefano Deledda, Bjørn C. Hauback, Shin-ichi Orimo   +5 more
doaj   +1 more source

Unraveling Hydride‐Driven Multiphasic Reduction Toward Tunable Germanium Structures for Lithium‐Ion Batteries

Advanced Science, EarlyView.
The sodium hydride (NaH)‐mediated reduction of germanium dioxide yields distinct Ge structures depending on the amount of reductant, revealing the dual roles of NaH in the reduction pathways. The synthesized Ge under off‐stoichiometric conditions exhibits a porous morphology and reduced crystallinity, which effectively mitigates volume expansion during
Gijung Lee, Jieun Kang, Jin Yong Kwon, Woori Bae, Noh‐Moon Lee, Byeongho Park, Yujin Park, Changwan Sun, Jihee Yoon, Hyungmin Park, Bonjae Koo, Jin Woo Yi, Jaegeon Ryu   +12 more
wiley   +1 more source

Chemical Upcycling of Nitrile Butadiene Rubbers to Polyamines and Polyols by Chemoselective Catalytic Hydrogenation

Angewandte Chemie, EarlyView.
We demonstrate here the transformation of NBR (Nitrile butadiene rubber) including post‐consumer waste sourced from nitrile gloves and o‐rings into polyamines and polyols via ruthenium catalyzed hydrogenation. ABSTRACT We report here two new approaches for the chemical recycling/upcycling of nitrile butadiene rubber (NBR) to make either polyamines or ...
Alejandra Sophia Lozano Perez, Raymundo Marcial‐Hernandez, Harini Sampathkumar, Oluchi Emenike, Ketan Pancholi, Claire N. Brodie, Daniel M. Dawson, Amit Kumar   +7 more
wiley   +2 more sources

Hydrogen absorption in metal hydrides: A dual-head tree-based framework for material class classification

International Journal of Thermofluids
Metal hydrides represent a highly promising alternative for hydrogen storage due to their favorable absorption properties and relatively moderate requirements in terms of temperature and pressure during the uptake stage.
Zaid Allal, Hassan N. Noura, Flavien Vernier, Ola Salman, Khaled Chahine   +4 more
doaj   +1 more source

Rare Earth Borohydrides—Crystal Structures and Thermal Properties

Energies, 2017
Rare earth (RE) borohydrides have received considerable attention during the past ten years as possible hydrogen storage materials due to their relatively high gravimetric hydrogen density. This review illustrates the rich chemistry, structural diversity
Christoph Frommen, Magnus H. Sørby, Michael Heere, Terry D. Humphries, Jørn E. Olsen, Bjørn C. Hauback   +5 more
doaj   +1 more source

Ambient Hydrocarbonylation of Olefins Enabled by Visible‐Light

Advanced Science, EarlyView.
A novel photo‐induced methodology for hydrocarbonylation has been established, resolving the inherent conflicts between competitive olefin and CO insertion in traditional methods that necessitate harsh conditions. Accordingly, an efficient and versatile hydrocarbonylation of olefins enabled by visible‐light irradiation under ambient conditions has been
Hongchi Liu, Tianze Zhang, Hanmin Huang
wiley   +1 more source

Navigating Nitration Chemistry: A Practical Guide to Reagents, Mechanisms, and Selectivity

Angewandte Chemie, EarlyView.
This review highlights key contributions of modern nitration chemistry, emphasizing sustainable mechanistic platforms and comparing the performance of both organic and inorganic reagents across aromatic, ipso‐, olefin, alkyne, and heteroatom nitration. It provides the community with a clearer, unified perspective on current advances and facilitates the
Harry Lecomte, Anthony J. Fernandes, Dmitry Katayev   +2 more
wiley   +2 more sources

Moderate Temperature Dense Phase Hydrogen Storage Materials within the US Department of Energy (DOE) H2 Storage Program: Trends toward Future Development

Crystals, 2012
Hydrogen has many positive attributes that make it a viable choice to augment the current portfolio of combustion-based fuels, especially when considering reducing pollution and greenhouse gas (GHG) emissions.
Scott McWhorter, Kathleen O’Malley, Jesse Adams, Grace Ordaz, Katie Randolph, Ned T. Stetson   +5 more
doaj   +1 more source