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Multi‐Li+ Coordination for Superior Room‐Temperature Ionic Conductivity in PEO Solid Electrolytes

open access: yesAdvanced Materials, EarlyView.
A phosphonate‐functionalized polycarboxylate ether (P‐PCE) is introduced into PEO electrolytes to induce multi‐Li+ ions coordination, which effectively dissociates lithium salts, liberates Li+ from the strong chelation by PEO chains, and promotes fast Li+ hopping between adjacent coordination sites. Simultaneously, this design establishes dynamic, high‐
Hengming Yan   +11 more
wiley   +1 more source
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Composite solid electrolytes

Russian Journal of Electrochemistry, 2010
Studies of composite ionic conductors are overviewed. Mechanisms of defect formation at ionic crystal surfaces and at interphase boundaries in the composites are discussed; the Stern model that allows calculating surface potential has been involved.
N. F. Uvarov   +2 more
openaire   +1 more source

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