Results 191 to 200 of about 566,161 (272)

Aromatic Pummerer‐Promoted Stereospecific Cross‐Coupling of Thiazoles With Boronic Esters

open access: yesAngewandte Chemie, EarlyView.
A lithiation–borylation–aromatic Pummerer (LiBAP) strategy enables stereospecific, C5‐selective C(sp2)–C(sp3) cross‐coupling of thiazoles with boronic esters. By using exocyclic sulfoxide activation to overcome the low nucleophilicity that frustrates SEAr‐type coupling, the method delivers enantioenriched alkylated thiazoles bearing a versatile C2 ...
Mark John P. Mandigma   +4 more
wiley   +2 more sources

Beyond the Camera: Epidermal Sensor Platforms for Intelligent Facial Expression Recognition and Interactive Human Monitoring

open access: yesAdvanced Intelligent Systems, EarlyView.
Skin‐conformal epidermal sensors enable camera‐free intelligent facial monitoring by converting facial deformation and muscle activity into electrical signals through piezoresistive, capacitive, electrophysiologic, and self‐powered mechanisms. Coupled with artificial intelligence (AI), these platforms support facial expression recognition, human ...
Jeehyun Joung   +5 more
wiley   +1 more source

Fluxional Monomers Remodel Crystallinity at Low Loadings in Diketopyrrolopyrrole Co‐Thienothiophene Conjugated Polymers

open access: yesAngewandte Chemie, EarlyView.
Bullvalene is a fluxional molecule capable of adopting numerous conformations spontaneously; just like a Rubik's Cube. In this paper, we explore the incorporation of bullvalene into the backbone of a highly rigid conjugated polymer semiconductor and observe that the inherent fluxionality reduces average crystallite size.
Shine H. Huang   +7 more
wiley   +2 more sources

Hybrid Granular–Elastomer Jamming With Confinement‐Mediated Stiffening

open access: yesAdvanced Intelligent Systems, EarlyView.
A granular–elastomer hybrid jamming medium enables isotropic, repeatable stiffness modulation by exploiting vacuum‐induced confinement of an elastomeric network rather than particle friction. The actuator supports large 3D deformations (bending, folding, and twisting), retains programmed shapes when unjammed, and achieves an ~8× stiffness increase and ...
Hwayeong Jeong, Jamie Paik, Jung Kim
wiley   +1 more source

From Atoms to Reactors: A Critical Review of a Decade of Machine Learning in Heterogeneous Catalysis (2017–2026)

open access: yesAngewandte Chemie, EarlyView.
Machine learning has digitalized heterogeneous catalysis from the top of the length scale downward: prediction at the atom and the material is now mature, yet the reactor and the process remain the open frontier. This critical review traces a decade of progress across the full catalytic value chain and asks where the next decade of impact must be won ...
Rafael Larraz, Avelino Corma
wiley   +2 more sources

Biomimetic Nanomedicine for Aging‐Impaired Bone Regeneration: From Microenvironmental Dysfunction to Precision Therapeutics

open access: yesAdvanced NanoBiomed Research, EarlyView.
Aging disrupts the cellular, immune, vascular, and neural processes required for bone regeneration. This review connects these pathological barriers with biomimetic nanomedicine design, highlighting strategies for cellular rejuvenation, immune modulation, vascular regeneration, and neuro–bone coupling.
Zeyu Wang   +12 more
wiley   +1 more source

In Vitro Selection of Functional Neoproteins Containing Highly Fluorinated Cores

open access: yesAngewandte Chemie, EarlyView.
The generation of neoproteins—functional proteins containing unnatural amino acids—is a key goal in synthetic biology. We develop a platform to discover neoproteins with specified bioactivity from trillion‐member sequence libraries, using genetic code reprogramming, in vitro selection and microwave peptide synthesis.
Adam Beattie   +5 more
wiley   +2 more sources

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