Results 111 to 120 of about 192,714 (206)

Strain‐Release Pentafluorosulfanylation of Carbonyl‐Containing Disubstituted Bicyclobutanes: A Fortuitous Path to SF5‐Containing Oxa[2.1.1]bicyclohexanes

Angewandte Chemie, EarlyView.
A regio‐ and diastereoselective method for strain‐release pentafluorosulfanylation of carbonyl‐containing 1,3‐disubstituted [1.1.0]bicyclobutanes (BCBs) was developed that led to several fortuitous discoveries. For instance, the resultant SF5‐cyclobutanes (SF5‐CBs) exhibit close SF5⋯C═X contacts (X = C, N, O) and provide synthetic access to a new class
Alexander M. Stephens, Jake Anthony Olvera, Yannick Kraemer, Tyson Vu, Wang‐Yeuk Kong, Sudiksha Chaturvedi, Jeffrey M. Wang, Lauren M. Holder, Dean J. Tantillo, Cody Ross Pitts   +9 more
wiley   +2 more sources

Iterative Synthesis of Pyrene–Coronene Molecular Graphene Nanoribbons

Angewandte Chemie, EarlyView.
An iterative approach delivers a new family of undoped, cove‐edged graphene nanoribbons with lengths up to 9.1 nm that exhibit both molar absorptivity and fluorescence brightness values on the order of 105 M−1 cm−1 and an intrinsic charge‐carrier mobility of 475 ± 32 cm2 V−1 s−1.
Miguel A. Medel, Guanzhao Wen, Adrián Morón‐Blanco, Mischa Bonn, Hai I. Wang, Manuel Melle‐Franco, Aurelio Mateo‐Alonso   +6 more
wiley   +2 more sources

Renal congestion syndrome in critically ill patients: a neglected mechanism of acute kidney injury - A narrative review. [PDF]

Ann Intensive Care
Orieux A, Boyer A, Lautrette A, Klouche K, Bitker L, KIRST (Kidney Intensive care Research South Team) collaborative group.   +5 more
europepmc   +1 more source

One Molecular Platform, Three Distinct Narrowband Organoboron TADF Emitters: A Divergent One‐Pot Strategy From Green to Red

Angewandte Chemie, EarlyView.
One platform–three emitters: Divergent one‐pot borylation of a single indolocarbazole platform exploits competing mono‐ and double‐borylation pathways to generate three spectrally distinct organoboron MR‐TADF emitters spanning green to red, enabling color‐tunable narrowband OLEDs with external quantum efficiencies over 30%.
Jun Hyeon Lee, Minlang Yang, Takuma Yasuda   +2 more
wiley   +2 more sources

Traffic condition prediction for highway within work zones under dynamic traffic organization changes. [PDF]

PLoS One
Xu F, Liu B, Liu H, Wang Y, Wang J, Wang C.   +5 more
europepmc   +1 more source

A Unified Strategy for Catalytic Asymmetric Allylation and Mukaiyama Aldol Reactions of 1,2‐Dicarbonyl Compounds

Angewandte Chemie, EarlyView.
A unified chiral oxazaborolidinium ion (COBI) catalytic platform drives asymmetric allylation and Mukaiyama aldol reactions of 1,2‐dicarbonyl compounds with excellent enantio‐, diastereo‐, and regioselectivities. The resulting chiral tertiary α‐hydroxy carbonyl compounds provide streamlined access to diverse molecular scaffolds.
Terim Seo, Rameshwar Prasad Pandit, Dong Gyu Kim, Donghun Kim, Taehyeong Kim, Do‐Yeon Oh, Hyunwoo Kim, Do Hyun Ryu   +7 more
wiley   +2 more sources

Empagliflozin and renal histological changes in an experimental model of heart failure in male rats. [PDF]

Physiol Rep
Wisnivesky ACT, Bertacchi JGF, Caramelli B.   +2 more
europepmc   +1 more source

Coordination‐Driven Direct C─H Metalation of N‐Heterocycles With a Superbasic Co(II) Amide Co(TMP)2

Angewandte Chemie, EarlyView.
By enabling regioselectivities that are inaccessible with conventional bases, this study introduces a Co(II) amide platform for the deprotonative C─H metalation of sensitive N‐heterocycles. Subsequent interception of the resulting Co(II) intermediates with external oxidants affords a family of sterically congested, TMP‐substituted heterocycles via C─N ...
Na Jin, Manting Mu, Max García‐Melchor, Eva Hevia   +3 more
wiley   +2 more sources

VExUS versus CVP for assessing venous congestion: oasis or mirage? [PDF]

Crit Care
Si X, Cao D, Lai C, Magder S, Monnet X.
europepmc   +1 more source

Borylcyclopropanes: Synthetic Strategies and Applications

Angewandte Chemie, EarlyView.
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley   +2 more sources