Results 221 to 230 of about 625,749 (287)

Asymmetric Reduction of Unactivated Alkenes

open access: yesChemistry – A European Journal, EarlyView.
Unactivated alkenes rank among the most inert functional groups in synthesis and their selective reduction remains challenging. This Review charts the evolution from classical metal‐catalyzed hydrogenation to radical hydrogen atom transfer (HAT) and emerging biocatalytic concepts, highlighting how complementary mechanistic strategies, including the ...
Nico D. Fessner   +3 more
wiley   +1 more source

VExUS Point-of-Care Ultrasound Tool to Detect Changes in Volume Status: A Prospective Observational Study. [PDF]

open access: yesJACC Adv
Leyba K   +13 more
europepmc   +1 more source

Benzo[cd]azulenyl: A Structural Isomer of Phenalenyl—Synthesis and Properties of Its Tri‐tert‐butyl‐substituted Derivative and Formation of a Thermal‐ and Photoresponsive σ‐Dimer

open access: yesChemistry – A European Journal, EarlyView.
Benzo[cd]azulenyl, a nonalternant isomer of phenalenyl, is identified as a new member of the nonalternant hydrocarbon radical family. The tri‐tert‐butyl substituted derivative forms a stable σ‐dimer in the solid state. Upon exposure to external stimuli such as light and heat, the σ‐bond of the dimer dissociates, producing the monomeric radical.
Kaho Takeuchi   +2 more
wiley   +1 more source

A DFT Study on the Mechanism of Selective Formation of Substituted Azepines From 1‐Azabutadienes and Cyclopropanes

open access: yesChemistry – A European Journal, EarlyView.
The origin of the unusual regioselectivity in the Mg‐catalyzed cyclization of azadiene‐type imines with cyclopropanes is elucidated by DFT calculations. Although five‐membered rings are typically favored, energy decomposition analysis reveals that severe steric congestion induces a highly distorted transition state, rendering the five‐membered pathway ...
Ryo Kobayashi   +5 more
wiley   +1 more source

Artificial intelligence-based characterization of multi-organ ultrasound congestion across the heart failure Spectrum. [PDF]

open access: yesEur Heart J Imaging Methods Pract
Del Punta L   +7 more
europepmc   +1 more source

State‐of‐the‐Art and Synthetic Challenges for Hydrosilane Production

open access: yesChemistry – A European Journal, EarlyView.
The synthesis of hydrosilanes is currently energy intensive and their recycling is not considered. However, these compounds are important in many industrial fields but also for the valorization of oxygenated waste, towards a circular economy. This review compares the available synthetic routes and highlights the remaining challenges for the production ...
Gabriel Durin   +3 more
wiley   +1 more source

Fluid responsiveness and changes in venous congestion and lung water during volume expansion in critically ill patients: a multicentre observational study. [PDF]

open access: yesCrit Care
Si X   +20 more
europepmc   +1 more source

Quetiapine induced severe nasal congestion - case report. [PDF]

open access: yesScand J Child Adolesc Psychiatr Psychol
Jensen KG, Andersen K.
europepmc   +1 more source

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