Repurposing Biocatalysts to Control Radical Polymerizations [PDF]
Reversible-deactivation radical polymerizations (controlled radical polymerizations) have revolutionized and revitalized the field of polymer synthesis. While enzymes and other biologically derived catalysts have long been known to initiate free radical polymerizations, the ability of peroxidases, hemoglobin, laccases, enzyme-mimetics, chlorophylls ...
Kyle J. Rodriguez +5 more
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Photomediated controlled radical polymerization [PDF]
Photomediated controlled radical polymerization is a versatile method to prepare, under mild conditions, various well-defined polymers with complex architecture, such as block and graft copolymers, sequence-controlled polymers, or hybrid materials via surface initiated polymerization.
Pan, Xiangcheng +5 more
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Non-steady scaling model for the kinetics of the photo-induced free radical polymerization of crosslinking networks [PDF]
Recently, a semi-empirical scaling model was introduced to account for the free-radical polymerization kinetics of acrylated urethane precursors in the solid-state.
Roose, Patrice +2 more
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Reversible addition fragmentation chain transfer polymerization - RAFT [PDF]
The fundamentals of controlled radical polymerization are presented in this review. The paper focuses on reversible addition fragmentation chain transfer (RAFT) polymerization.
Avramović Milena +3 more
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Molecular imprinting in hydrogels using reversible addition-fragmentation chain transfer polymerization and continuous flow micro-reactor [PDF]
BACKGROUND Stimuli responsive imprinted hydrogel micro-particles were prepared using reversible addition-fragmentation chain transfer polymerization for targeting genotoxic impurity aminopyridine in aqueous environment using a continuous flow micro ...
Costa, Mário Rui +5 more
core +1 more source
This article describes some selected results of my 30 years as an industrial researcher. During this time, I had the chance to work on many very different projects.
Peter Nesvadba
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Polymers Interfacing with Biology
The development of various controlled radical polymerization techniques as well as site- and residue specific strategies to modify peptides/proteins with synthetic polymers have made polymer chemistry a powerful tool to address materials ...
Frederik Wurm, Harm-Anton Klok
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Atom Transfer RaAtom Transfer Radical Polymerization of Methyl Methacrylate Using Bis(2-dodecylsulfanyl-ethyl)-Amine/Copper Bromide: Kinetic Study [PDF]
Hypothesis: In controlled polymerization methods, atom transfer radical polymerization (ATRP) is one of the most successful methods for the polymerization of various monomers with the controlled pattern. Effect of some important parameters on kinetics of
Farnoosh Karimi +2 more
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In-situ syntheses of graft copolymers by metal-free strategies: combination of photoATRP and ROP
A completely metal-free and environmentally friendly strategy is demonstrated for the preparation of graft copolymers by combining photoinduced Atom Transfer Radical Polymerization (ATRP) and Ring Opening Polymerization (ROP).
Gorkem Yilmaz
doaj +1 more source
Catalytic polymeric nanoreactors : more than a solid supported catalyst [PDF]
Polymeric nanostructures can be synthesized where the catalytic motif is covalently attached within the core domain and protected from the environment by a polymeric shell.
Bosman, Liu, Wang, Yan
core +2 more sources

