Results 31 to 40 of about 78,340 (285)

Stereospecific cationic RAFT polymerization of bulky vinyl ethers and stereoblock poly(vinyl alcohol) via mechanistic transformation to radical RAFT polymerization of vinyl acetate

Giant, 2021
The simultaneous control of molecular weight and tacticity in cationic polymerization remains challenging. Here, we propose a new approach for stereospecific living cationic polymerization by combining cationic reversible addition-fragmentation chain ...
Mineto Uchiyama, Kotaro Satoh, Masami Kamigaito   +2 more
doaj   +1 more source

Photoinduced Synthesis of Block Copolymers by Combination of Atom Transfer Radical Polymerization and Photoinduced Radical Oxidation/Addition/Deactivation

Journal of the Turkish Chemical Society, Section A: Chemistry, 2018
A new polymerization mechanistic transformation strategy, combining two different controlled polymerization techniques of different modes, atom transfer radical polymerization (ATRP) and photoinduced radical oxidation/addition/deactivation (PROAD), is ...
Mustafa Çiftci
doaj   +1 more source

Biofunctional and Biomimetic Polymer Brushes Prepared via Surface-Initiated Atom Transfer Radical Polymerization

CHIMIA, 2008
Surface-initiated controlled radical polymerization is a powerful strategy to tailor the chemical and physical surface properties of materials.
Laurent Lavanant, Harm-Anton Klok
doaj   +1 more source

Biocatalytic nanoparticles for the stabilization of degassed single electron transfer-living radical pickering emulsion polymerizations

Nature Communications, 2020
The use of solid particles to stabilize Pickering emulsions is a particularly attractive avenue, but oxygen sensitivity remains an obstacle in controlled polymerization reactions.
Adrian Moreno, Mika H. Sipponen
doaj   +1 more source

Absolut “copper catalyzation perfected”; robust living polymerization of NIPAM : Guinness is good for SET-LRP [PDF]

The controlled polymerization of N-isopropyl acrylamide (NIPAM) is reported in a range of international beers, wine, ciders and spirits utilizing Cu(0)-mediated living radical polymerization (SET-LRP).
Anastasaki, Athina, Becer, C. Remzi, Burns, James (James Adam), Collins, J. (Jennifer), Droesbeke, Martjin, Girault, Mony, Godfrey, Jamie, Haddleton, Alice J., Haddleton, David M., Houben, Claudia, Kiviaho, Jenny K., Li, Muxiu, Li, Zaidong, Lloyd, Danielle J., McEwan, Kayleigh A., McHale, Ronan, Nikolaou, Vasiliki, Nurumbetov, Gabit, Randev, Rajan, Risangud, Nuttapol, Simula, Alexandre, Summers, Christopher J., Waldron, Christopher, Wilson, Paul, Yilmaz, Gokhan, Zhang, Qiang   +25 more
core   +1 more source

Sequential curing of amine-acrylate-methacrylate mixtures based on selective aza-Michael addition followed by radical photopolymerization [PDF]

, 2016
Dual curing systems find various uses in industry with the process flexibility they provide which allows tailoring properties at different curing stages in accordance with application requirements. A safe and efficient dual curing scheme is proposed here
Fernández Francos, Xavier, Konuray, Ali Osman, Ramis Juan, Xavier, Serra Albet, Àngels   +3 more
core   +1 more source

Controlled Radical Polymerization toward Ultra-High Molecular Weight by Rationally Designed Borane Radical Initiators

Cell Reports Physical Science, 2020
Summary: Ultra-high-molecular-weight (UHMW) polymers can display outstanding properties; however, it is challenging to synthesize UHMW polymers by using external free radical initiators.
Yinling Wang, Qianyi Wang, Xiangcheng Pan   +2 more
doaj   +1 more source

Copper(0)-mediated radical polymerisation in a self-generating biphasic system [PDF]

, 2013
Herein, we demonstrate the synthesis of well-defined poly(n-alkyl acrylate)s via copper(0)-mediated radical polymerisation in a self-generating biphasic system. During the polymerisation of n-butyl acrylate in DMSO, the polymer phase separates to yield a
Amir Atme, Athina Anastasaki, Biedroń, Boyer, Boyer, Carmichael, Christopher Waldron, Ciampolini, Contel, Cyrille Boyer, D'Hooge, David Haddleton, Ding, Faucher, Grimes, Haddleton, Haddleton, Haddleton, Haddleton, Hong, Jakubowski, Kamigaito, Kickelbick, Konkolewicz, Levere, Lou, Matyjaszewski, Matyjaszewski, Michael R. Whittaker, Mohan, Mueller, Mueller, Nguyen, Nguyen, Nguyen, Nguyen, Nguyen, Noda, Nystroem, Otazaghine, Paul Wilson, Per B. Zetterlund, Percec, Perreault, Pintauer, Pintauer, Popescu, Ragagnin, Sarbu, Shen, Silverstein, Soeriyadi, Tsarevsky, Wright   +53 more
core   +1 more source

Controlled/living radical polymerization

Materials Today, 2005
Until a little more than a decade ago, controlled/living radical polymerization (CRP) would have been an oxymoron. Full control over all aspects of radical polymerization was deemed well-nigh impossible because radical termination reactions occur at diffusion-controlled rates.
Matyjaszewski, Krzysztof, Spanswick, James   +1 more
openaire   +1 more source

Controlled Radical Polymerization in Emulsion [PDF]

Macromolecules, 1997
Themolecularweightdis-tribution of the polymer synthesized in an emulsionpolymerizationprocesscanbecontrolledbyinfluencingtheentryandexitcoefficientsandchain-stoppingreac-tions by means of varying initiator concentration,numberofparticles,andparticlesizedistributionorbymeansofadditionofachain-transferagent.Anovelradicalpolymerizationmethodthatisableto ...
Bon, S.A.F., Bosveld, M., Klumperman, B., German, A.L.   +3 more
openaire   +2 more sources