Results 111 to 120 of about 15,723 (248)

White‐Light‐Mediated Imidazole Catalysis Toward Terpene‐Based Thermosets

open access: yesAngewandte Chemie, EarlyView.
White‐light irradiation enables the photoinitiator‐free curing of fully bio‐based terpene epoxy–anhydride systems. A light‐induced switch in epoxide ring‐opening selectivity leads to colorless, transparent thermosets with enhanced thermomechanical performance, revealing an unexpected pathway for sustainable terpene‐based network formation.
Chenxi Zhang   +3 more
wiley   +2 more sources

Fluorescent Hydrogel‐Based Strain Sensor With Machine Learning‐Augmented Performance

open access: yesAdvanced Intelligent Discovery, EarlyView.
Fluorescent hydrogel strain sensor based on carbon quantum dots enabling optical readout of deformation through strain‐dependent emission changes, coupled with Random Forest analysis to capture nonlinear fluorescence‐concentration relationships and identify optimal sensing conditions. Hydrogels are ideal matrices for bio‐integrated wearable sensors due
Tailai Chen   +4 more
wiley   +1 more source

Attractive Ni…O Interactions Enable Non‐Alternating Ethylene‐Carbon Monoxide Copolymerization

open access: yesAngewandte Chemie, EarlyView.
Attractive Ni···O interactions are established in phosphine‐imidated and phosphine‐phenolate nickel catalysts, enabling non‐alternating ethylene‐carbon monoxide copolymerization, resulting in superior CO tolerance, productivity and stability compared to the state‐of‐the‐art benchmark.
Yajun Zhao   +5 more
wiley   +2 more sources

Smart Bioinspired Material‐Based Actuators: Current Challenges and Prospects

open access: yesAdvanced Intelligent Systems, Volume 7, Issue 3, March 2025.
This work gathers, in a review style, an extensive and comprehensive literature overview on the development of autonomous actuators based on synthetic materials, bringing together valuable knowledge from several studies. Furthermore, the article identifies the fundamental principles of actuation mechanisms and defines key parameters to address the size
Alejandro Palacios   +4 more
wiley   +1 more source

On‐Demand Deconstructable Thermosets Through Cleavable Comonomer and Thermolatent Base Synergy

open access: yesAngewandte Chemie, EarlyView.
Thermosets, valued for their chemical and mechanical properties, resist recycling due to their cross‐linked structure. Weak bonds via comonomers enable degradability, but diffusion limits effectiveness. We incorporate thermolatent bases before polymerization (thermal or 3D‐VAT printing).
Sophia Kouider   +15 more
wiley   +2 more sources

Scalable ω‐Substituted α‐Olefins via Living Chain Transfer Telomerization: A Platform for Next Generation Polyolefins

open access: yesAngewandte Chemie, EarlyView.
A highly versatile and general strategy is presented for the scalable production of practical quantities of ω‐substituted α‐olefins using tris(ω‐substituted alkyl)aluminum telogens that are readily available through a “green” synthesis from commodity triisobutylaluminum and ethene as the taxogen. These new α‐olefins can be designed and used as monomers
Lauren G. Logue   +4 more
wiley   +2 more sources

Radical Copolymerization of Vinyl Ketones. I. Copolymerization with Acrylonitrile [PDF]

open access: yesPolymer Journal, 1976
Acosta, José Luis   +3 more
openaire   +1 more source

Degradable Alternating Copolymers With Strained Cyclobutane Backbones via Photocontrolled RAFT Polymerization

open access: yesAngewandte Chemie, EarlyView.
A photocontrolled RAFT strategy enables the alternating copolymerization of 1,3‐disubstituted bicyclo[1.1.0]butanes with electron‐deficient comonomers, affording well‐defined copolymers bearing strained cyclobutane backbones. A high degree of alternation, tunable molecular weights, and excellent end‐group fidelity are achieved through a CTA‐mediated ...
Xia Hu   +4 more
wiley   +2 more sources

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