Results 91 to 100 of about 15,592 (253)

Computer modeling of the synthesis of styrene–butadiene rubber: Influence of the feed of a chain transfer agent on the characteristics of the product

open access: yesТонкие химические технологии
Objectives. To develop mathematical approaches and algorithms for analyzing the influence of various methods for feeding a chain transfer agent to a cascade of reactors, taking into account the choice of feed points on the characteristics of the final ...
T. A. Mikhailova, S. A. Mustafina
doaj   +1 more source

Dinuclear Group 4 Metallocene Catalysts of the Type [(Cp2M)2(μ‐Me)(μ‐C2R)]: Structure‐Activity Relationships in Ethylene Polymerization

open access: yesChemistry – A European Journal, EarlyView.
Homo‐ and heterodinuclear group 4 metallocene complexes of the type [(Cp2M)2(μ‐Me)(μ‐C2R)] (M = Ti, Zr) are active catalysts for the polymerization of ethylene in the presence of aluminium‐free activators. The catalytically active species are proposed to have dinuclear character and depending on the type of activator, unique reactivity was observed ...
Hanan Al Hamwi   +8 more
wiley   +1 more source

Unravelling the initiator‐only stage in alginate grafting: Radical‐induced depolymerization and its impact on acrylamide grafting efficiency

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract Free‐radical grafting of natural polymers often assumes that initiators only create active sites before monomer addition. We tested this by exposing sodium alginate to potassium persulphate (KPS) under typical grafting conditions without monomer (acrylamide).
Gustavo P. Zago, João B. P. Soares
wiley   +1 more source

Tunable amylopectin graft copolymers for flocculating and dewatering iron ore tailings

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract Polyacrylamide (PAM), the standard flocculant for mining tailings, often produces turbid supernatants and poorly dewatered sediments, limiting water reuse and tailings densification. We synthesized amylopectin‐graft‐poly[(2‐methacryloyloxy)ethyl]trimethylammonium chloride (AP‐g‐PMETAC) copolymers with systematically varied graft frequency (N = 
Gustavo P. Zago   +2 more
wiley   +1 more source

Biobased Random Copolymers From Furandicarboxylic Acid Isomers: Proof of Concept for an Integrated Biorefinery Approach Toward Outstanding Sustainable Food Packaging

open access: yesGlobal Challenges
This work explored the industrial potential of an alternative green synthetic route to obtain 2,5‐furandicarboxylic acid (2,5‐FDCA) via a Henkel‐type disproportionation reaction developed by Thiyagarajan et al., meant to produce furan, and up to 30% of 2,
Enrico Bianchi   +5 more
doaj   +1 more source

Learning Strategies from Nature's Blueprint to Cyclic Carbonate Synthesis

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
The development of sustainable synthetic methods for cyclic carbonates draws inspiration from nature, focusing on eco‐friendly processes and renewable resources like CO2 and biomass. This review explore various CO2 activation mechanisms, green chemistry principles, and green catalysts.
Erika Saccullo   +4 more
wiley   +1 more source

Circular and Bio‐Sourced Polymers for Energy Applications: Natural Feedstocks, Recycling, and Upcycling Routes

open access: yesEcoEnergy, EarlyView.
This review provides a critical comparative analysis of circular and bio‐sourced polymers for energy storage, systematically evaluating natural feedstocks alongside recycling and upcycling strategies for battery components. Key structure–property–performance relationships and inherent trade‐offs between sustainability metrics and electrochemical ...
Priyank Sinha   +3 more
wiley   +1 more source

Recent Advance for PVDF Based Flexible Piezoelectric Sensors

open access: yesEcoEnergy, EarlyView.
This review focus on the structural regulation of PVDF via boundary confinement, blending regulation, electric‐field‐assisted orientation, and chemical modification for flexible piezoelectric sensors. ABSTRACT The rapid advancement of flexible electronics, wearable devices, and biomedical engineering has spurred increasing demand for sensor materials ...
Chaoran Tan   +4 more
wiley   +1 more source

Synergistic Design of Composite Ionogels With Enhanced Thermoelectric Properties, Mechanical Stretchability, and Sustainable Recyclability

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
While flexible TE devices hold promise for converting low‐grade waste heat (e.g., from human skin or electronics) into usable electricity, existing materials suffer from three major limitations: 1) poor mechanical stretchability (failing to match human skin's elongation, ~20–30%), limiting wearability; 2) tradeoffs between thermoelectric efficiency (e ...
Mingqi Liu   +5 more
wiley   +1 more source

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