Results 71 to 80 of about 15,723 (248)

Solvent effects in copolymerization

open access: yesMacromolecular Rapid Communications, 1995
AbstractExtension of the Mayo‐Lewis Model of copolymerization concerning solvent effects in free‐radical polymerization is discussed on the basis of the bootstrap and penultimate unit effects.
ODRISCOLL, KF   +3 more
openaire   +4 more sources

Selenophene π‐Bridge Enables Balanced Ambipolar Transport in High‐Performance Organic Electrochemical Transistors

open access: yesAdvanced Science, EarlyView.
We synthesized a high‐performance balanced ambipolar OECT polymer, P(gTDPPSe), via selenophene π‐bridge engineering. The selenophene π‐bridge enhances backbone planarity and optimizes the energy levels for doping, enabling high and balanced p/n‐type transconductance‐a key factor for high‐gain complementary inverters.
Guichuan Zhu   +4 more
wiley   +1 more source

Real‐Time Stress Visualization of Hydrogels Enabled by Supramolecularly Switched Stretch‐Induced Phase Separation

open access: yesAdvanced Science, EarlyView.
Supramolecular hydrogels enable real‐time visualization of mechanical stress through supramolecular switching mechanotransduction. Adamantane‐modified cellulose functions as a responsive domain that undergoes an on–off transition between hydrated and dehydrated states via reversible β‐cyclodextrin–adamantane complexation and decomplexation.
Sooyeon Noh   +7 more
wiley   +1 more source

An Implantable Phototriggered Prodrug Depot Patch Enables Actively Programmable Drug Release for Post‐Myocardial Infarction Therapy

open access: yesAdvanced Science, EarlyView.
An implantable phototriggered prodrug depot patch (iPDP) is presented that enables actively programmable drug release post‐implantation. Covalently conjugated prodrug ensures minimal leakage; illumination parameters serve as a code to precisely control dose per release.
Haipeng Lu   +10 more
wiley   +1 more source

Copolymerization of Hydrophilic and Hydrophobic Monomers in Water Assisted by Cyclodextrins

open access: yesNano Select
To facilitate the copolymerization of both hydrophobic and hydrophilic monomers in aqueous media, cyclodextrins (CDs) are introduced to form inclusion complexes with the hydrophobic monomers.
Alexy Sanseigne   +3 more
doaj   +1 more source

Revealing the Ion Regulation Effect of Zwitterionic All‐Solid‐State Electrolytes in Lithium Metal Batteries

open access: yesAdvanced Science, EarlyView.
This study investigates zwitterionic all‐solid‐state electrolytes, demonstrating strong carboxyl‐Li+ interaction that forms “ion‐enrichment pathway”‐like domains and manipulates Li+ deposition. Additionally, surface‐enriched zwitterions generate a dual‐layer SEI with an inner Li2O‐rich and outer LiF‐rich structure. Through ionic flux regulation and SEI
Wentao Xie   +13 more
wiley   +1 more source

High‐Performance Transparent Solid Polymer Electrolyte Based on Copolymer of Deep Eutectic Electrolyte and Methyl Methacrylate for Electrochemical Devices

open access: yesAdvanced Science, EarlyView.
A copolymerization strategy using a polymerizable deep eutectic electrolyte with MMA forms efficient ion‐transport pathways while maintaining excellent transparency. The solid polymer electrolyte simultaneously achieves 17.8 MPa mechanical strength and 1.43 mS cm−1 ionic conductivity, enhancing long‐term cycling stability in Li|LFP batteries and ...
Tingting Chen   +6 more
wiley   +1 more source

“Schizomorphic” Emulsion Copolymerization Particles

open access: yesMacromolecular Rapid Communications, 2011
AbstractCryo‐electron microscopy, atomic force microscopy, and light microscopy investigations provide experimental evidence that amphiphilic emulsion copolymerization particles change their morphology in dependence on concentration. The shape of the particles is spherical at solids content above 1%, but it changes to rod‐like, ring‐like, and web‐like ...
Weber, Nancy   +4 more
openaire   +5 more sources

Bidirectional Disulfide Metathesis Enables Recycling of High‐Performance Thermoset Networks

open access: yesAdvanced Science, EarlyView.
A cyclic aromatic disulfide comonomer enables dual‐mode recyclable pDCPD thermosets through bidirectional disulfide metathesis. The resulting networks combine enhanced mechanical performance with thermal reprocessability and chemical depolymerization into reusable oligomeric fragments, allowing regeneration of high‐performance thermosets with minimal ...
Bohan Li   +8 more
wiley   +1 more source

Study of the structural, thermal, rheological and film properties of functional copolymers of hydroxyethyl acrylate and methyl methacrylate

open access: yesPolímeros
New functional polymers will be prepared using alkyd resins having high solid content (environmentally friendly) and comb-type structural morphology.
María Mejia, Edwin Murillo
doaj   +1 more source

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