Results 51 to 60 of about 83,698 (348)

Effect of Monomer Mixture Composition on TiCl4-Al(i-C4H9)3 Catalytic System Activity in Butadiene–Isoprene Copolymerization: A Theoretical Study

open access: yesComputation
Divinylisoprene rubber, a copolymer of butadiene and isoprene, is used as raw material for rubber technical products, combining isoprene rubber’s elasticity and butadiene rubber’s wear resistance.
Konstantin A. Tereshchenko   +4 more
doaj   +1 more source

Synthesis and Thermal Properties of Novel Biodegradable ABCBA Pentablock Copolymers from Poly (Ethylene glycol), L-Lactide and p-Dioxanone [PDF]

open access: yesIranian Journal of Chemistry & Chemical Engineering, 2010
In this work, new biodegradable ABCBA type pentablock copolymers with different mole ratio of L-lactide and PPDO-b-PEG-b-PPDO triblock copolymer were synthesized and characterized.
Jamshid Mohammadi-Rovshandeh   +4 more
doaj  

"Synthesis and properties of poly(butylene succinate) based copolymers and multi-block copolymers"

open access: yesHecheng xiangjiao gongye, 2022
Polybutylene succinate (PBS) and a series of multi-block hydroxyl-terminated diol copolymers were synthesized by a "one-step"method with succinic anhydride (SAA) and 1,4-butanediol (BDO) as monomers, and terminal hydroxy diols as copolymer monomer.
MAO Xin, L■ Bo, ZHAO Peng-ju, YU Hai-long, CUI Jin-feng, GUO Jun-hong, YANG Bao-ping
doaj   +1 more source

Growth and dissolution of macromolecular Markov chains

open access: yes, 2016
The kinetics and thermodynamics of free living copolymerization are studied for processes with rates depending on k monomeric units of the macromolecular chain behind the unit that is attached or detached. In this case, the sequence of monomeric units in
Gaspard, Pierre
core   +1 more source

Preparation of multiblock copolymers via step-wise addition of l-lactide and trimethylene carbonate. [PDF]

open access: yes, 2018
Poly(l-lactide) (PLA) is a bioderived and biodegradable polymer that has limited applications due to its hard and brittle nature. Incorporation of 1,3-trimethylene carbonate into PLA, in a block copolymer fashion, improves the mechanical properties ...
Abubekerov, Mark   +5 more
core   +1 more source

Strategies for Loading and Releasing Peptide Therapeutics in Biodegradable Carriers

open access: yesAdvanced Functional Materials, EarlyView.
A biodegradable carrier‐based peptide delivery system is a powerful treatment platform for diverse diseases, owing to its superior therapeutic efficacy and low toxicity. This review examines the conventional peptide‐loaded carrier fabrication process and its current limitations.
Wookyoung Jang, Ki Wan Bong
wiley   +1 more source

Sensitized Triplet Exciton Generation in Nanostructured Polymer Scintillators: Toward Improved γ/Neutron Discrimination

open access: yesAdvanced Functional Materials, EarlyView.
Rapid γ/neutron discrimination through PSD is achieved in liquid droplet containing nanostructured polymeric scintillator where a TTA‐active dye is dissolved. The inclusion of a properly selected and dosed sensitizer metalated porphyrin enhances discrimination sensitivity and speed by doubling the density of annihilating triplets and increasing the ...
Luca Pollice   +9 more
wiley   +1 more source

Kinetic resolution of racemic {alpha}-olefins with ansa-zirconocene polymerization catalysts: Enantiomorphic site vs. chain end control [PDF]

open access: yes, 2006
Copolymerization of racemic {alpha}-olefins with ethylene and propylene was carried out in the presence of enantiopure C1-symmetric ansa metallocene, {1,2-(SiMe2)2({eta}5-C5H-3,5-(CHMe2)2)({eta}5-C5H3)}ZrCl2 to probe the effect of the polymer chain end ...
Bercaw, John E., Byers, Jeffery A.
core   +1 more source

Design and Synthesis of Peptide‐Polyester Conjugates for Cell‐Mediated Scaffold Degradation

open access: yesAdvanced Healthcare Materials, EarlyView.
This work describes polycaprolactone (PCL)‐based biomaterials engineered to degrade in response to cell‐secreted proteases. A fast‐degrading peptide (Fast) sequence is integrated into a PCL conjugate backbone to produce a biomaterial that is selectively degraded by multiple cell types compared to its scrambled control (ScrFast).
Korina Vida G. Sinad   +7 more
wiley   +1 more source

Polyisoprene Captured Sulfur Nanocomposite Materials for High-Areal-Capacity Lithium Sulfur Battery [PDF]

open access: yes, 2019
A polyisoprene-sulfur (PIPS) copolymer and nano sulfur composite material (90 wt % sulfur) is synthesized through inverse vulcanization of PIP polymer with micrometer-sized sulfur particles for high-areal-capacity lithium sulfur batteries.
Fang, C   +7 more
core   +1 more source

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