Results 51 to 60 of about 15,723 (248)
The synthesis and structural analysis of (Me3SiC5H4)TiCl2(OAr) [OAr = O-2,6-iPr2-4-RC6H2; R = H, SiEt3] revealed that it exhibits higher catalytic activities than (tBuC5H4)TiCl2(OAr), Cp*TiCl2(OAr), with efficient comonomer incorporation in ethylene ...
Tiantian Huang +3 more
doaj +1 more source
Highly Entangled Bottlebrush Polymer Networks
Bottlebrush polymers are difficult to entangle, enabling ultrasoft yet brittle networks. We report highly entangled bottlebrush elastomers that remain ultrasoft (∼1 kPa) yet stretch to ∼1800% and exhibit exceptional fatigue resistance. Their intrinsic fatigue strength—fatigue threshold normalized by modulus—surpasses that of highly entangled linear ...
Myoeum Kim +3 more
wiley +1 more source
Copolymerization of Ethylene and Propylene Using 4th Generation Ziegler- Natta Catalyst: Influence of Cocatalyst, External Electron Donor and Hydrogen [PDF]
Copolymerization of ethylene and propylene was investigated using a 4th generation phthalate Ziegler-Natta catalyst in normal hexane in a Buchi reactor.
R. Mehtarani +4 more
doaj +1 more source
Free-Radical Copolymerization VII. Reinterpretation of Velocity-of-Copolymerization Data [PDF]
Velocity-of-copolymerization data available in the literature were reinterpreted on the basis of the current notions that the penultimate-unit effect with respect to absolute values of propagation rate constant (but not with respect to the monomer reactivity ratios) is a general rule, and that the termination step is diffusion-controlled, i.e., normal.
Fukuda, Takeshi +3 more
openaire +1 more source
Aqueous Zn(II) Salphen metallofibers decorated with PNIPAM undergo reversible, multi‐stimuli‐responsive hierarchical bundling. This higher‐order structuring kinetically stabilizes the otherwise fragile assemblies against dilution, acidic hydrolysis, and transmetallation, enables selective sorting of responsive fibers, and programs hydrogelation at ...
Merlin R. Stühler +5 more
wiley +1 more source
The synergistic integration of rigid polyacrylamide (PAM) and flexible poly(N,N‐dimethylacrylamide) (PDMA) phases offers exceptional toughness to suppress lithium dendrites, simultaneously enhancing mechanical strength and ionic conductivity. ABSTRACT Gel polymer electrolytes for lithium‐metal batteries face an inherent trade‐off between mechanical ...
Hao Long +6 more
wiley +1 more source
The transition from cryogenic distillation to polymeric sorbents for light hydrocarbon purification is crucial for energy and environmental sustainability. The polymeric sorbents are engineered to separate gas mixtures based on their specific properties.
Kelechi Festus +9 more
wiley +1 more source
A simple and reliable method was proposed for rapid detecting ciprofloxacin, based on molecularly imprinted technology. The molecularly imprinted ciprofloxacin hydrochloride (CPX) sensor was prepared by electropolymerization of pyrrole (Py) and o ...
Changling Yan +6 more
doaj +1 more source
Extrusion‐based bioprinting (EBB) has emerged as a versatile biofabrication platform capable of precisely depositing bioinks composed of biomaterials, cells, and bioactive agents to generate patient‐specific, biomimetic skin constructs. This paper presents a state‐of‐the‐art and forward‐looking overview of EBB for wound healing, encompassing printing ...
Hien‐Phuong Le +4 more
wiley +1 more source
Influence of initiator types and emulsion polymerization techniques to particle size of copolymerization styrene-butyl acrylate-methyl methacrylate. Copoly(styrene/butyl acrylic/methyl methacrylic) was prepared by emulsion polymerization method.
Ariyanti Sarwono, Emil Budianto
doaj

