Solvent effects in copolymerization [PDF]
AbstractExtension of the Mayo‐Lewis Model of copolymerization concerning solvent effects in free‐radical polymerization is discussed on the basis of the bootstrap and penultimate unit effects.
ODRISCOLL, KF +3 more
openaire +5 more sources
CoPolDB: A Copolymerization Database for Radical Polymerization [PDF]
Although a large amount of knowledge on copolymers and coplymerization has been already accumulated in literature, there are no freely available databases with a proper graphical user interface (GUI) on copolymerization. Focusing on copolymerization with
Nanyi, Zhu +4 more
core +1 more source
Copper-Catalyzed C(3+1) Copolymerization of Propargyl Carbonates and Aryldiazomethanes [PDF]
Controlling the composition and sequence during diazo copolymerization with vinyl or acetylenic monomers is challenging. Here we disclose a Cu-catalyzed C(3+1) copolymerization reaction using propargyl carbonates and aryldiazomethanes derived from N ...
Hao-Ze, Su +3 more
core +2 more sources
Copolymerization Reactivity Ratio Inference: Determining Confidence Contours in Parameter Space via a Bayesian Hierarchical Approach [PDF]
Confidence contours in parameter space are a helpful tool to compare and classify determined estimators. For more intricate parameter estimations of non-linear nature or complex error structures, the procedure of determining confidence contours is a ...
Robert, Reischke
core +1 more source
Emergent sequence biasing in step-growth copolymerization: influence of non-bonded interactions and comonomer reactivities [PDF]
The phase behavior and material properties of copolymers are intrinsically dependent on their primary comonomer sequences. Achieving precise control over monomer sequence in synthetic copolymerizations is challenging, as sequence determination is ...
Kateri, DuBay +5 more
core +2 more sources
Synthesis of Degradable Polyacetals via an Intramolecular Phosphonium Borane Lewis Pair Catalyzed Copolymerization of Epoxides with o-Phthaladehyde [PDF]
An intramolecular phosphonium borane Lewis pair (PBB-Br) was used for the copolymerization of o-phthalaldehyde (OPA) with epoxides under mild conditions.
Minmin, Shi +4 more
core +2 more sources
The mixture of synthetic and natural materials yields a material with improved physical-chemical properties. One way of obtaining this kind of material is through graft copolymerization.
Alfredo Carlos Martinez-Arellano +5 more
doaj +1 more source
Tertiary Amines Paired with Trialkyl Boranes: A Simple Organocatalyst for Fully Alternating Copolymerization of Carbon Dioxide and Propylene Oxide [PDF]
Metal-free synthesis of fully alternating polycarbonates from carbon dioxide (CO2) and epoxides is highly desired but a huge challenge. Here, we disclose the combination of tertiary amines with trialkyl boranes for completely alternating copolymerization
Ben Zhong, Tang +7 more
core +1 more source
The structure of polyolefin has an important influence on its performance and application. Ethylene/1-hexene copolymerization is one of the important ways to control the structure of the polyolefin.
Yusheng Xing +6 more
doaj +1 more source

