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A hexaicosametallic copper(ii) phosphonate
Dalton Transactions, 2013Structure and characterization of [Cu26{2,3,5,6-(Me)4C6H-CH2-PO3}18(μ2-OH)4(μ3-OH)6(μ4-Cl)6(μ-OH2)2(OH2)2(MeCN)4]·6MeCN·15H2O (1) is reported. Complex 1 is the largest discrete molecular homometallic transition metal phosphonate assembly. Remarkably, this gigantic molecular phosphonate has been prepared at room temperature using a normal solution ...
Vadapalli, Chandrasekhar +5 more
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A hexadecameric copper(II) phosphonate
Dalton Transactions, 2009The first example of a hexadecanuclear copper(II) phosphonate containing pyrazole, hydroxide and acetate ancillary ligands has been assembled in a reaction involving copper(II) nitrate, pyrazole, t-butylphosphonic acid and triethylamine.
Vadapalli, Chandrasekhar +1 more
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Antilupus activity of copper (II)
Experimental pathology, 1985Collagen-like syndrome was induced in rats by oral hydralazine administration during 5 months. After 4 months, a subgroup of rats was shifted from the standard diet to the diet supplemented with copper (II) (60 micrograms of copper per g of pellet) as copper sulphate. A decreased serum copper concentration was noted, LE cells were observed in the blood
A, Jendryczko, M, Drozdz, K, Magner
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Thermal studies of copper(II) fumarate and copper(II) terephthalate
Thermochimica Acta, 2005Abstract Copper(II) fumarate (Cu(OOCC2H2COO)) and copper(II) terephthalate (Cu(OOCC6H4COO)) have been synthesized. Their heat capacity has been measured by adiabatic calorimetry between 13 and 300 K and their magnetic susceptibility determined with a SQUID magnetometer between 5 and 300 K.
Mikako INOUE +3 more
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Copper(II) Chloride-Copper(II) Oxide
2001(CuCl2) [7447-39-4] Cl2Cu (MW 134.45) InChI = 1S/2ClH.Cu/h2*1H;/q;;+2/p-2 InChIKey = ORTQZVOHEJQUHG-UHFFFAOYSA-L (CuO) [1317-38-0] CuO (MW 79.54) InChI = 1S/Cu.O InChIKey = QPLDLSVMHZLSFG-UHFFFAOYSA-N (carbonyl deprotection reagent; allows transformation of thioacetals, α-heterosubstituted sulfides, and selenoacetals to ...
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Binding of Copper(II) to Pilocarpine†
Journal of Chemical Research, 1997The speciation in the pilocarpine-Cu II system, as studied by potentiometric and spectroscopic techniques on aqueous solutions, is described.
Chruscinska E +3 more
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(−)-Sparteine copper(II) diacetate
Acta Crystallographica Section C Crystal Structure Communications, 2000The chiral nitrogen-chelating alkaloid (−)-sparteine acts as a bidentate ligand, reacting with copper(II) acetate in ethanol to form the title complex, [Cu(CH3COO)2(C15H26N2)], with the two acetate groups occupying the remaining coordination sites in a monodentate fashion to produce a distorted four-coordinate tetrahedral structure.
, Lee, , Chung, , Kwon, , Choi
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Double Hydrated Cobalt(II) Copper(II) and Nickel(II) Copper(II) Ammine Diphosphates
Russian Journal of Applied Chemistry, 2005Synthesis of amorphous and crystalline double hydrated cobalt copper and nickel copper ammine diphosphates with a coordination structure is described.
L. V. Voitenko +2 more
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Histidine-Copper (II) Complexes
Nature, 1959STABILITY constants are known for copper complexes of most of the naturally occurring α-amino-acids. However, although it is of considerable biochemical interest, the copper–histidine system has not been interpreted in detail. The system is anomalous, probably because, although the metal can co-ordinate to the amino, imidazole or carboxyl groups in ...
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Inorganica Chimica Acta, 2005
Abstract Copper(II) cations coordinated with PMDTA (pentamethyldiethylenetriamine) and TMEDA (tetramethylethylenediamine) possess a high synthetic potential. The synthesis of these cations was carried out by metathesis reactions with silver salts. The cationic copper(II) complexes, [Cu(PMDTA)(Me2CO)Cl]+, [Cu(PMDTA)(H2O)Cl]+, [Cu(PMDTA)(DMF)]+, [Cu ...
Günter Margraf +3 more
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Abstract Copper(II) cations coordinated with PMDTA (pentamethyldiethylenetriamine) and TMEDA (tetramethylethylenediamine) possess a high synthetic potential. The synthesis of these cations was carried out by metathesis reactions with silver salts. The cationic copper(II) complexes, [Cu(PMDTA)(Me2CO)Cl]+, [Cu(PMDTA)(H2O)Cl]+, [Cu(PMDTA)(DMF)]+, [Cu ...
Günter Margraf +3 more
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