Results 211 to 220 of about 135,415 (266)
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Copper(II) complexes of imidazolinone herbicides
Inorganica Chimica Acta, 1997Abstract The copper(II) complexes formed by the imidazolinone herbicide Imazapyr or (±)-2-4-isopropyl-(4-methyl-5-oxo-2-imidazolin-2-yl)-nicotinic acid (H 2 imz) are described. The compounds isolated in the solid state confirm that Imazapyr is a versatile bipy-like ligand able to chelate the metal ion through two different donor sets.
Liliana Strinna Erre +4 more
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New copper(II) complexes of Creatinine
Thermochimica Acta, 1999Abstract The importance of Creatinine in clinical chemistry is well recognized: its level in serum and urine is indicative of renal function (Creatinine Clearance Test) and it is the final metabolic product of Creatine, that participates in energy flow in the muscle tissues.
MATERAZZI, Stefano +3 more
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A phenoxyl radical complex of copper(ii)
Chemical Communications, 2001A new N,O-bidentate pro-ligand (HL), [ML2] (M = Cu, Zn) and [CuL2][BF4] have been synthesised; [CuL2].4DMF and [CuL2][BF4].2CH2Cl2 have been crystallographically and spectroscopically characterised; these data indicate that [CuL2]+ cations are constituted as [Cu2+(L.)(L-)]+ and involve the phenoxyl radical L..
L, Benisvy +8 more
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Copper(I) and Copper(II) Complexes of Creatinine
Journal of Coordination Chemistry, 1990Abstract A Cu(II) complex of creatinine (creat) was prepared, with formula Cu(creat)2Cl2, as well as a Cu(I) creatinine complex, Cu(creat H_1)(EtNH2).H2O(EtNH2 = ethylamine). The Cu(II) adduct is complexed with neutral creatinine and IR evidence suggests a tetrahedral geometry for the complex with bonding to the ring amino nitrogen atom. Diamagnetic Cu(
W. J. Birdsall, Bruce A. Weber
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Copper(II) and copper(I) complexes of benzenecarbothioamides
Transition Metal Chemistry, 1988Copper(II) salts react with benzenecarbothioamide(BCTA);N,N-dimethylbencenecarbothioamide (DMBCTA) andN,N-diethylbenzenecarbothioamide (DEBCTA) to give complexes with 1∶1, 2∶1, 3∶1 ligand/metal stoichiometric ratios, and a diamagnetic complex [Cu2(DEBCTA)Br4]2 which appears to contains copper(I). These compounds were characterized by elemental analyses,
Azucena Garc�a-Onrubia +3 more
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Histidine-Copper (II) Complexes
Nature, 1959STABILITY constants are known for copper complexes of most of the naturally occurring α-amino-acids. However, although it is of considerable biochemical interest, the copper–histidine system has not been interpreted in detail. The system is anomalous, probably because, although the metal can co-ordinate to the amino, imidazole or carboxyl groups in ...
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Cyano-bridged Homodinuclear Copper(II) Complexes
Inorganic Chemistry, 2011The synthesis and structural analysis (single crystal X-ray data) of two mononuclear ([Cu(L(1))(CN)]BF(4) and [Cu(L(3))(CN)](BF(4))) and three related, cyanide-bridged homodinuclear complexes ([{Cu(L(1))}(2)(CN)](BF(4))(3)·1.35 H(2)O, [{Cu(L(2))}(2)(CN)](BF(4))(3) and [{Ni(L(3))}(2)(CN)](BF(4))(3)) with a tetradentate (L(1)) and two isomeric ...
Atanasov, Mihail +5 more
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Copper(ii) complexes of rat amylin fragments
Dalton Transactions, 2011The fragments of rat amylin rIAPP(17-29) (Ac-VRSSNNLGPVLPP-NH(2)), rIAPP(17-22) (Ac-VRSSNN-NH(2)), rIAPP(19-22) (Ac-SSNN-NH(2)) and rIAPP(17-20) (Ac-VRSS-NH(2)) together with the related mutant peptides (Ac-VASS-NH(2) and Ac-VRAA-NH(2)) have been synthesized and their copper(II) complexes studied by potentiometric, UV-Vis, CD and EPR spectroscopic ...
C Kállay +10 more
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On the Complexation of Copper (II) Ion with 2‐Hydroxybenzamide
Annali di Chimica, 2007AbstractThe complexation of the Cu2+ ion with 2‐Hydroxybenzamide (salicylamide, HL) has been studied, at 25 °C, by potentiometric measurements with a glass electrode in NaClO4 media for ionic strength ranging from 0.5 to 3 mol/dm3. The data are consistent with the formation of the complexes CuH‐1(HL)+, CuH‐2(HL)2, Cu2H‐2(HL)22+ and CuH‐2(HL). The minor
PORTO R, FURIA, Emilia
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On the structure of manganese (II)- and copper (II)-histidine complexes
Archives of Biochemistry and Biophysics, 1969Abstract l -Histidine offers three groups as potential binding sites for metal ions: the imidazole, amino, and carboxylic acid groups. For stereochemical and geometric reasons, Cu(II) can bind strongly to only two of the three groups at a given moment.
H, Sigel, R, Griesser, D B, McCormick
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