Results 161 to 170 of about 902,655 (232)

Breaking the Polarity–Coordination Coupling in Electrolyte Design for High‐Voltage Lithium Batteries

open access: yesAdvanced Energy Materials, EarlyView.
Steric and electronic co‐regulation of 2,2,2‐trifluoro‐N, N‐dimethylethylamide (DMTFA) decouples high polarity from strong Li+ coordination, creating an anion‐mediated pseudo‐weakly solvating electrolyte. This design lowers Li+ desolvation barriers, enhances Li+ mobility, and builds B‐, F‐, and N‐rich inorganic interphases, enabling stable 3.0–4.6 V ...
Xue Li   +9 more
wiley   +1 more source

Characterizing Biopolymer Electrolytes in Zinc–Air Batteries: Challenges, Best Practices, and a Robust Workflow Guiding Future Research Paths

open access: yesAdvanced Energy Materials, EarlyView.
Bio‐based gel polymer electrolytes promise sustainable, mechanically adaptable zinc–air batteries, yet their progress is constrained by inconsistent characterization. This review critically links formulation, structure, interfaces, and cell performance, identifies methodological gaps under alkaline operating conditions, and proposes application ...
Matteo Milanesi   +6 more
wiley   +1 more source

Aldehyde-Aminotriazole Condensation Products as Novel Corrosion Inhibitors for Mild Steel in Hydrochloric Acid. [PDF]

open access: yesPolymers (Basel)
Bazanov DR   +8 more
europepmc   +1 more source

Separating Hydrogen Evolution From Electroplating in Zn Metal Batteries Using Scanning Electrochemical Microscopy

open access: yesAdvanced Energy Materials, EarlyView.
Operando SECM decouples hydrogen evolution from other degradation pathways in Zn metal batteries by quantifying its contribution during Zn electrodeposition. Although HER is shown to account for only a minor fraction of the irreversible charge loss, it remains a key indicator of interfacial evolution and by‐product formation governing cycling ...
J. T. Simon   +8 more
wiley   +1 more source

Stabilizing Zinc Anodes via a Zeolite‐Induced Localized Supersaturated Electrolyte Interface

open access: yesAngewandte Chemie, EarlyView.
A low‐Si/Al‐ratio ZSM‐5 (LZ5) interphase induces a localized supersaturated electrolyte interface on Zn, with a local Zn2+ concentration exceeding 10 M in a 1 M ZnSO4 bulk electrolyte. Continuous Zn2+ enrichment within the zeolite nanochannels creates an H2O‐deficient, anion‐enriched solvation environment, promoting rapid desolvation, uniform ...
Xiaoqi Liu   +12 more
wiley   +2 more sources

Electric Double Layer Engineering Induces O‐Down Interfacial Water Reorientation for Efficient and Long‐Term Seawater Electrolysis

open access: yesAdvanced Energy Materials, EarlyView.
The additive EDTMPS inhibits hydroxides deposition by chelating with Ca2+/Mg2+. It also disrupts the hydrogen bond network of interfacial water and expands the thickness of electric double layer, promoting more free water to flip into adsorbable O‐down configuration.
Tongzhou Li   +7 more
wiley   +1 more source

Caging Polyhalide Anions in Polycyclodextrin for Long‐Lasting Aqueous Zinc‐Iodine Batteries

open access: yesAngewandte Chemie, EarlyView.
We demonstrated poly(β‐cyclodextrin) gel as an ideal host material that effectively contains and releases polyhalide anions in aqueous zinc‐iodine batteries. Such a unique host‐guest chemistry prevents the shuttle effect of polyhalides. The corresponding batteries can operate via both 2e and 4e storage, attaining 60,000 cycles with more than 99% and 85%
Shangxu Jiang   +7 more
wiley   +2 more sources

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